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At 303 K ethanol has a vapour pressure of about 0.118 atm., acetic acid has the vapour pressure of about 0.039 atm., and ethyl iodide has a vapour pressure of about 0.263 atm. Which of the following represents the correct order of increasing normal boiling point ?
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5.At a given temperature and pressure 2 volumes of A combine with 5 volumes of B to form 2 volmes of C and 1 volume. A combine with one volume of B to form 2 volumes of D. The formula of C is
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The vol. of 20 gms of nitrogen at N.T.P.
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Kinetic theory of gases postulates :
A. The molecules in a gas are in stationary state
B. The molecules in a gas exert appreciable attraction on each other
C. The molecules move in a random motion with widely different velocities
D. The molecules in a gas collide against each other as well as the wall of the container, but do not change their direction of motion
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In a unit cell of cesium chloride the arrangement of cesium ions is
B. hexagonal close packed
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In a dose packed arrangement of N spheres, the number of tetrahedral holes are
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Chloroform and benzene form a pair of miscible liquids. These can be separated by
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When there is more deviation in the behaviour of a gas from ideal gas equation PV = nRT
A. at high temperature and low pressure
B. at low temperature and high pressure
C. at high temperature and high pressure
D. at low temperature and low pressure
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The number of tetrahedral and octahedral voids per atom in a crystal lattice are, respectively
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Absolute zero is the temperature at which
B. all gases become liquid
C. all substances are solid
D. molecular motion ceases
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In the gas equation PV = xT, x is a constant. The value of the constant depends upon
C. type values of T and P
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According to Avogadro's hypothesis equal volumes of two gases under the same conditions of temperature and pressure contain
A. Equal number of electrons
D. Equal number of molecules
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The number of atoms per unit cell in bcc arrangement is
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Certain volume of a gas exerts on its walls some pressure at a particular temperature. It has been found that by reducing the volume of the gas to half its original value, the pressure becomes I twice that the initial value of constant temperature. This happens because
A. More number of a gas molecules strike the surface per second
B. Velocity of the gas molecules increases
C. Gas molecules attract each other
D. Weight of the gas increase with volume
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The vapour density of completely dissociated sociated would be
A. Determined by the amount of solid used in the experiment
B. Triple to that of
D. Slightly less than half of that of
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The critical temperature of a substance is defined as
A. the temperature above which the substance decomposes
B. the temperature above which the substance can exist only as a gas
C. melting point of the substance
D. boiling point of the substanc
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Indicate the most viscous liquid of the following
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Avogadro stated that under similar conditions of temperature and pressure equal volumes of all gases contain equal number of
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An open vessel at 37°C is heated until 3/5 of the air in it has been expelled. Assuming that the volume of the vessel remains constant the temperature to which the vessel is heated is
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A vessel containing 10 litre of air at atmospheric pressure is connected to an evacuated 9 litre vessel The resulting pressure will be
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7.Which of the following sets of conditions represent the easiest way to liquefy a gas?
A. Low temperature and high pressure
B. High temperature and low pressure
C. High temperature and low pressure
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What is the vapour pressure of benzoyl chloride at its boiling point (197°C)?
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Equal weights of methane and hydrogen are mixed in an empty container at 25°C. The fraction of the total pressure exerted by methane is
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Which of the following statement wrong?
A. In solid state molecules, atoms or ions are held with a strong force of attraction and are in a fixed position
B. In liquid state the molecules, atom or ions are held with a strong force and have a restricted motion
C. In gaseous states, the molecules are randomly arranged and are apart from each other
D. Solid, liquid and gaseous states have different movement is particles
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Which of the following contains the same number of atoms as 12 gms: of Magnesium (Atomic weights : Mg = 24, C = 12, Ca = 40)
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Four 1 litre flasks are separately filled with hydrogen, helium, oxygen and ozone gases at the same temperature and pressure. The ratio of total number of atoms of these gases present in the different flasks would be
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Three dimensional array of points in space is called
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The vapour density of ozone would be
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At what temperature, the root mean square velocity of oxygen molecules is equal to that of at 27°C?
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Of the following properties, the magnitude of one must always increase with temperature. The property is