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4

A solid metallic block weighing 5 kg has an initial temperature of 500°C. 40 kg of water initially at 25°C is contained in a perfectly insulated tank. The metallic block is brought into contact with water. Both of them come to equilibrium. Specific heat of block material is 0.4 kJ.kg-1. K-1. Ignoring the effect of expansion and contraction and also the heat capacity to tank, the total entropy change in kJ.kg-1, K-1 is

A. -1.87

B. 0

C. 1.26

D. 3.91

Correct Answer :

B. 0


Related Questions

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4

If two gases have same reduced temperature and reduced pressure, then they will have the same

A. Volume

B. Mass

C. Critical temperature

D. None of these

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4

Degree of freedom of the system ice-watervapour will be

A. 0

B. 1

C. 2

D. 3

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4

There is a change in __________ during the phase transition.

A. Volume

B. Pressure

C. Temperature

D. All a, b & c

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4

After throttling, gas temperature

A. Decreases

B. Increases

C. Remain same

D. May increase or decrease; depends on the nature of the gas

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4

If heat contents of CH4, C2H4 and C3H8 are -17.9, 12.5 and -24.8 kcal/mole respectively, than ΔH for the reaction CH4(g) + C2H4(g) C3H8(g) will be __________ Kcal.

A. -19.4

B. -30.2

C. 55.2

D. -55.2

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4

If the molar heat capacities (Cp or Cv) of the reactants and products of a chemical reaction are identical, then, with the increase in temperature, the heat of reaction will

A. Increase

B. Decrease

C. Remain unaltered

D. Increase or decrease; depends on the particular reaction

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4

When a gas in a vessel expands, its internal energy decreases. The process involved is

A. Reversible

B. Irreversible

C. Isothermal

D. Adiabatic

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4

Chemical engineering thermodynamics is concerned with the __________ in/of chemical processes.

A. Reaction mechanism

B. Calculation of rates

C. Energy transformation from one form to another

D. None of these

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4

Throttling (Joule-Thomson effect) process is a constant __________ process.

A. Enthalpy

B. Entropy

C. Pressure

D. None of these

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4

Dry ice is

A. Moisture free ice

B. Solid helium

C. Solid carbon dioxide

D. None of these

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4

Which is a state function?

A. Specific volume

B. Work

C. Pressure

D. Temperature

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4

Steam undergoes isentropic expansion in a turbine from 5000 kPa and 400°C (entropy = 6.65 kJ/kg K) to 150 kPa) (entropy of saturated liquid = 1.4336 kJ/kg. K, entropy of saturated vapour = 7.2234 kJ/kg. K) The exit condition of steam is

A. Superheated vapour

B. Partially condensed vapour with quality of 0.9

C. Saturated vapour

D. Partially condensed vapour with quality of 0.1

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4

The unit of equilibrium constant of a chemical reaction is the same as that of

A. Molar concentration

B. Temperature

C. Internal energy

D. None of these

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4

Extensive properties of a thermodynamic system depend upon the __________ of the system.

A. Specific volume

B. Temperature

C. Mass

D. Pressure

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4

Entropy of the system decreases, when

A. Snow melts into water

B. A gas expands spontaneously from high pressure to low pressure

C. Water is converted into ice

D. Both (B) & (C)

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4

For an isothermal reversible compression of an ideal gas

A. Only ΔE = 0

B. Only ΔH =0

C. ΔE = ΔH = 0

D. dQ = dE

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4

(∂E/∂T)V is the mathematical expression for

A. CV

B. Enthalpy change

C. Free energy change

D. None of these

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4

Enthalpy 'H' is defined as

A. H = E - PV

B. H = F - TS

C. H - E = PV

D. None of these

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4

The rate at which a substance reacts is proportional to its active mass and the rate of a chemical reaction is proportional to the product of active masses of the reacting substances. This is the

A. Lewis-Randall rule

B. Statement of Van't Hoff Equation

C. Le-Chatelier's principle

D. None of these

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4

The equation, PV = nRT, is best obeyed by gases at

A. Low pressure & high temperature

B. High pressure & low temperature

C. Low pressure & low temperature

D. None of these

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4

Pick out the wrong statement.

A. At constant pressure, solubility of a gas in a liquid diminishes with rise in temperature

B. Normally, the gases which are easily liquefied are more soluble in common solvents

C. The gases which are capable of forming ions in aqueous solution are much more soluble in water than in other solvents

D. At constant pressure, solubility of a gas in a liquid increases with rise in temperature

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4

Third law of thermodynamics is helpful in

A. Prediction of the extent of a chemical reaction

B. Calculating absolute entropies of substances at different temperature

C. Evaluating entropy changes of chemical reaction

D. Both (B) and (C)

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4

Work done in an adiabatic process between two states depends on the

A. Rate of heat transmission

B. Initial state only

C. End states only

D. None of these

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4

(1/V) (∂V/∂T)P is the mathematical expression

A. Joule-Thomson co-efficient

B. Specific heat at constant pressure (Cp)

C. co-efficient of thermal expansion

D. Specific heat at constant volume (CV)

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4

The expression for the work done for a reversible polytropic process can be used to obtain the expression for work done for all processes, except reversible __________ process.

A. Isobaric

B. Isothermal

C. Adiabatic

D. None of these

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4

Co-efficient of Performance (COP) of a refrigerator is the ratio of the

A. Work required to refrigeration obtained

B. Refrigeration obtained to the work required

C. Lower to higher temperature

D. Higher to lower temperature

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4

For a cyclic process, a fixed ratio between heat and work

A. Always exists

B. May exist

C. Never exists

D. Is difficult to predict

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4

The co-efficient of performance (COP) of a refrigerating system, which is its index of performance, is defined as the ratio of useful refrigeration to the net work. The units of __________ and COP are the same.

A. Kinematic viscosity

B. Work

C. Temperature

D. None of these

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4

Which of the following has the least thermal efficiency?

A. Steam engine

B. Carnot engine

C. Diesel engine

D. Otto engine

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4

In case of a reversible process (following pvn = constant), work obtained for trebling the volume (v1 = 1 m3 and v23 m3) is maximum, when the value of 'n' is

A. 0

B. 1

C. y = 1.44

D. 1.66