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4

As pressure approaches zero, the ratio of fugacity to pressure (f/P) for a gas approaches

A. Zero

B. Unity

C. Infinity

D. An indeterminate value

Correct Answer :

B. Unity


Related Questions

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4

Which of the following is not affected by temperature changes?

A. Fugacity

B. Activity co-efficient

C. Free energy

D. None of these

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4

Cp - Cv = R is valid for __________ gases.

A. Ideal

B. Very high pressure

C. Very low temperature

D. All of the above

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4

Joule-Thomson co-efficient for a perfect gas is

A. Zero

B. Positive

C. Negative

D. None of these

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4

Critical compressibility factor for all substances

A. Are more or less constant (vary from 0.2 to 0.3)

B. Vary as square of the absolute temperature

C. Vary as square of the absolute pressure

D. None of these

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4

dW and dq are not the exact differential, because q and W are

A. State functions

B. Path functions

C. Intensive properties

D. Extensive properties

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4

All gases except __________ shows a cooling effect during throttling process at atmospheric temperature and pressure.

A. Oxygen

B. Nitrogen

C. Air

D. Hydrogen

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4

Mollier diagram is a plot of

A. Temperature vs. enthalpy

B. Temperature vs. enthalpy

C. Entropy vs. enthalpy

D. Temperature vs. internal energy

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4

Pick out the correct statement:

A. In an isothermal system, irreversible work is more than reversible work

B. Under reversible conditions, the adiabatic work is less than isothermal work

C. Heat, work, enthalpy and entropy are all 'state functions'

D. Matter and energy cannot be exchanged with the surroundings in a closed system

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4

What happens in a reversible adiabatic expansion process?

A. Heating takes place

B. Cooling takes place

C. Pressure is constant

D. Temperature is constant

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4

Free energy change of mixing two liquid substances is a function of the

A. Concentration of the constituents only

B. Quantities of the constituents only

C. Temperature only

D. All (A), (B) and (C)

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4

Equilibrium constant decreases as the temperature

A. Increases, for an exothermic reaction

B. Decreases, for an exothermic reaction

C. Increases, for an endothermic reaction

D. None of these

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4

At constant temperature and pressure, for one mole of a pure substance, the ratio of the free energy to the chemical potential is

A. Zero

B. One

C. Infinity

D. Negative

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4

In vapour compression refrigeration system, if the evaporator temperature and the condenser temperatures are -13°C and 37°C respectively, the Carnot COP will be

A. 5.2

B. 6.2

C. 0.168

D. Data insufficient, can't be found out

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4

The expression for entropy change given by, ΔS = - nR ln (P2/P1), holds good for

A. Expansion of a real gas

B. Reversible isothermal volume change

C. Heating of an ideal gas

D. Cooling of a real gas

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4

Which of the following identities can be most easily used to verify steam table data for superheated steam?

A. (∂T/∂V)S = (∂p/∂S)V

B. (∂T/∂P)S = (∂V/∂S)P

C. (∂P/∂T)V = (∂S/∂V)T

D. (∂V/∂T)P = -(∂S/∂P)T

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4

What is the value of ln y (where y = activity co-efficient) for ideal gases?

A. Zero

B. Unity

C. Infinity

D. Negative

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4

In Joule-Thomson porous plug experiment, the

A. Enthalpy does not remain constant

B. Entire apparatus is exposed to surroundings

C. Temperature remains constant

D. None of these

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4

Which of the following represents the Virial equation of state?

A. T = [RT/(V- b)] - [a/√T. V(V + b)]

B. PV/RT = 1 + (B/V) + (C/V2) + ……

C. n1u2 + μ2μ1 = 0

D. None of these

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4

Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature.

A. Decreases

B. Increases

C. Remains constant

D. Decreases logarithmically

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4

Pick out the wrong statement.

A. Surface tension of a substance vanishes at critical point, as there is no distinction between liquid and vapour phases at its critical point

B. Entropy of a system decreases with the evolution of heat

C. Change of internal energy is negative for exothermic reactions

D. The eccentric factor for all materials is always more than one

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4

Joule-Thomson co-efficient depends on the

A. Pressure

B. Temperature

C. Both (A) & (B)

D. Neither (A) nor (B)

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4

The root mean square speed of molecules of a gas is equal to (where, m = mass of the molecule K = Boltzmanns constant, T = absolute temperature)

A. √(2KT/m)

B. √(3KT/m)

C. √(6KT/m)

D. 3KT/m

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4

A/an __________ system is exemplified by a vessel containing a volatile liquid in contact with its vapor.

A. Isolated

B. Closed

C. Open

D. None of these

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4

The specific heat of saturated water vapour at 100°C is

A.

B. -ve

C. 0

D. +ve

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4

With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure

A. Increases

B. Decreases

C. Remain same

D. Decreases linearly

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4

The minimum number of phases that can exist in a system is

A. 0

B. 1

C. 2

D. 3

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4

Those solutions in which there is no volume change upon mixing the components in the liquid state and which, when diluted do not undergo any heat change (i.e. heat of dilution is zero), are called __________ solutions.

A. Ideal

B. Real

C. Isotonic

D. None of these

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4

Which of the following is not correct for a reversible adiabatic process?

A. TVγ-1 = constant

B. p1-γ.TY = constant

C. PVγ = constant

D. None of these

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4

For any system, what is the minimum number of degrees of freedom?

A. 0

B. 1

C. 2

D. 3

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4

Which of the following liquid metals has the highest thermal conductivity?

A. Molten sodium

B. Molten lead

C. Mercury

D. Molten potassium