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To which of the following mixtures is the Dalton's law of partial pressures not applicable?
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A balloon filled with ethane is pricked up with sharp point and quickly plunged into a tank of hydrogen at the same pressure. After some time balloon will
C. remain unchanged in size
D. have half its volume of the gas
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The critical temperature of a substance is defined as
A. the temperature above which the substance decomposes
B. the temperature above which the substance can exist only as a gas
C. melting point of the substance
D. boiling point of the substanc
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4
In a unit cell of cesium chloride the arrangement of cesium ions is
B. hexagonal close packed
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According to Avogadro's hypothesis equal volumes of two gases under the same conditions of temperature and pressure contain
A. Equal number of electrons
D. Equal number of molecules
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The number of N2 molecules present in 28 nitrogen is
C. 6 x approximately
D. 5 x approximately
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The number of molecules in 4.25 gm of ammonia are approximately
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The molecular weight of a volatile liquid can be determined by
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The number of atoms per unit cell in simple cubic, face centred cubic and body centred cubic arrangement are, respectively
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Which of the following is an example of covalent network solid?
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The pressure of the ideal gas is less than the real gas because of the
A. increase in the number of collisions
B. volume occupied by the molecules
C. inter-molecular attraction
D. finite size of molecules
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From the Dulong and Petit's law atomic weight is given by which one of the following relations?
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Indicate the most volatile liquid of the following:
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The coordination number of each sphere in hcp arrangement is
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The vapour density of a gas is 11.2. The volume occupied by 2.4 g of the gas at S.T.P wil be
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6.If the reactants and products both are in gaseous phase they bear a simple ratio in their
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Molecular formula of D in the above case is
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The mean free path of a gas molecule is the distance
A. between the two opposite walls of the container
B. through which the molecules travel in one second
C. through which molecules move between two consecutive collisions
D. travelled by all the molecules divided by the total number of molecules in a particular gas
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Which of the following will have low heat of fusion?
D. a network of covalent solid
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Gases deviate from the ideal behaviour because their molecules
A. possess negligible volume
B. have forces of attraction between them
D. are not attracted to one another
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Which of the following should be most viscous?
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The kinetic theory of gases predicts that total kinetic energy of a gaseous assembly depends upon the
B. temperature of the gas
D. pressure, temperature and volume of the gas
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The number of atoms per unit cell in bcc arrangement is
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In fluorite structure coordination number of calcium ions is
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Four 1 litre flasks are separately filled with the gases hydrogen, helium, oxygen and ozone at the same temperature and pressure, the ratio of total number of atoms of these gases present in the different flasks would be
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Match box has the symmetry of which of the following systems?
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If all the octahedral sites in a cubic close packed arrangement () are completelyfilled with cations, the empirical formula of the compound could then be
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For a given gas at temperature T and pressure P the root mean square velocity (RMS) is C; then at temperature T and pressure 3P the RMS is
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Which of the following contains the same number of atoms as 12 gms: of Magnesium (Atomic weights : Mg = 24, C = 12, Ca = 40)
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In a dose packed arrangement of N spheres, the number of tetrahedral holes are