Related Questions
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4
In case of the decomposition of hydroiodic acid (2HI H2 + I2), addition of H2 (at equilibrium condition) will
A. Increase the partial pressure of I2
B. Decrease the partial pressure of HI
C. Diminish the degree of dissociation of HI
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4
In the reaction, H2 +I2 2HI, addition of an inert gas will
A. Increase the partial pressure of H2
B. Increase the partial pressure of I2
C. Increase the total pressure and hence shift the equilibrium towards the right
D. Not affect the equilibrium conditions
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4
Degree of freedom of the system ice-watervapour will be
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4
A gas performs the maximum work, when it expands
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4
Rotary lime kiln is an example of a/an __________ system.
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The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1 is the activity co-efficient of component 1, is
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4
Entropy of an ideal gas depends upon its
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The main feature of Carnot refrigeration cycle is that, it
A. Does not need the addition of external work for its functioning
B. Transfers heat from high temperature to low temperature
C. Accomplishes the reverse effect of the heat engine
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4
Joule-Thomson co-efficient which is defined as, η = (∂T/∂P)H = 1/Cp (∂H/∂T)P, changes sign at a temperature known as inversion temperature. The value of Joule-Thomson co-efficient at inversion temperature is
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4
1m3 of an ideal gas at 500 K and 1000 kPa expands reversibly to 5 times its initial volume in an insulated container. If the specific heat capacity (at constant pressure) of the gas is 21 J/mole . K, the final temperature will be
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4
Work done is a
A. Property of the system
D. State description of a system
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In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is
D. Unpredictable; depends on the particular reaction
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Fugacity is a measure of the
A. Escaping tendencies of the same substance in different phases of a system
B. Relative volatility of a mixture of two miscible liquids
C. Behaviour of ideal gases
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Cv for an ideal gas
A. Does not depend upon temperature
B. Is independent of pressure only
C. Is independent of volume only
D. Is independent of both pressure and volume
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4
Solid and liquid phases of a substance are in equilibrium at the
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4 kg moles of an ideal gas expands in vacuum spontaneously. The work done is
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In a reversible process
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Gibbs phase rule finds application, when heat transfer occurs by
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The root mean square speed of molecules of a gas is equal to (where, m = mass of the molecule K = Boltzmanns constant, T = absolute temperature)
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The acentric factor of a materical, 'ω', is defined as ω = -log10(Prsat)Tr-1 = 0.7, where, Prsat = reduced vapor pressure, Tr = reduced temperature. The value of acentric factor is always
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4
Heat of formation of an element in its standard state is
D. A function of pressure
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The kinetic energy of gas molecule is zero at
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In a turbine, the fluid expands almost
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In an ideal gas mixture, fugacity of a species is equal to its
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A system undergoes a change from a given initial state to a given final state either by an irreversible process or by a reversible process, then (where, Δ S1 and Δ SR are the entropy changes of the system for the irreversible and reversible processes respectively)
B. Δ S1 is sometimes > Δ SR
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The total change in the enthalpy of a system is independent of the
A. Number of intermediate chemical reactions involved
B. Pressure and temperature
C. State of combination and aggregation in the beginning and at the end of the reaction
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The value of Cp & Cv respectively for monatomic gases in Kcal/kg Mole.°K are
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Which of the following represents the Virial equation of state?
A. T = [RT/(V- b)] - [a/√T. V(V + b)]
B. PV/RT = 1 + (B/V) + (C/V2) + ……
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4
Joule-Thomson effect i.e., a throttling process is a constant __________ process.
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Pick out the correct equation relating 'F' and 'A'.