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4

Gases deviate from the ideal behaviour because their molecules

A. possess negligible volume

B. have forces of attraction between them

C. are polyatomic

D. are not attracted to one another

Correct Answer :

B. have forces of attraction between them


Related Questions

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4

The Van der Waal's equation explains the behaviour of

A. ideal gases

B. real gases

C. vapours

D. non-real gases

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4

The radii of A+ and X- are 95 pm and 181 pm respectively. Coordination number of A+ is expected to be

A. 8

B. 6

C. 4

D. 3

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4

Indicate the most viscous liquid of the following

A. propanol-2

B. 1.2, ethandiol

C. 1.2,3 propentriol

D. ethanol

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4

The weight of 11.2 litres of CO2 at S.T.P. would be

A. 22 gms

B. 66 gms

C. 11 gms

D. 16 gms

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4

The limiting radii ratio for the tetrahedral geometry is

A. 0.155

B. 0.444

C. 0.732

D. 0.225

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4

What is the vapour pressure of benzoyl chloride at its boiling point (197°C)?

A. 760 torr

B. 380 torr

C. 197 torr

D. None of these

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4

The ionic radii of Mg+2  and O-2 are 0.66 A° and 1.40 A° , respectively. The most probable type of gteometry exhibited by MgO on the basis of radius ratio rule is

A. NaCl type

B. CsCl type

C. ZnS type

D. Boron oxide type

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4

Which of the following contains the same number of atoms as 12 gms: of Magnesium (Atomic weights : Mg = 24, C = 12, Ca = 40)

A. 10 gms of calcium

B. 20 gms of carbon

C. 20 gms of calcium

D. 12 gms of carbon

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4

Match box has the symmetry of which of the following systems?

A. Cubic

B. Orthorhombic

C. Tetragonal

D. Monoclinic

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4

The V.D. of a gas is 11.2 gm. The volume occupied by 11.2 gm. of this gas at N.T.P. is

A. 12 litre

B. 11.2 litres

C. 2.24 litres

D. 22.4 litres

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4

Arrange the following in order of increasing inter-molecular forces and boiling points:NH3,He,Cl2

A. He<Cl2<NH3

B. He>Cl2>NH3

C. Cl2<He<NH3

D. NH3<He<Cl2

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4

In NaCl type structure, the coordination number of the cation and anion are

A. 6 and 4

B. 6 and 6

C. 4 and 4

D. 8 and 4

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4

Of the following properties, the magnitude of one must always increase with temperature. The property is

A. vapour pressure

B. density

C. Hvap

D. surface tension

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4

The number of N2 molecules present in 28 nitrogen is

A. 2 x 10

B. 6 x 1022

C. 6 x 1023 approximately

D. 5 x 1030 approximately

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4

Which of the following is an amorphous solid?

A. NaCl

B.  CaF2

C. Diamond

D. Glass

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4

When there is more deviation in the behaviour of a gas from ideal gas equation PV = nRT

A. at high temperature and low pressure

B. at low temperature and high pressure

C. at high temperature and high pressure

D. at low temperature and low pressure

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4

Indicate the most volatile liquid of the following:

A. CH3OH

B. CH3OCH3

C.  H2O

D. CH3CH2OCH2CH3

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4

The vapour density of a gas is 11.2. The volume occupied by 2.4 g of the gas at S.T.P wil be

A. 2.4 litres

B. 3.6 litres

C. 2.24 litres

D. 11.2 liters

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4

If the temperature and pressure remain unchanged the volume of O2obtained by the decomposition of a certain volume of SO2 will be

A. Triple the volume of SO2

B. Half the volume of SO2

C. Equal to the volume of SO2

D. One third the volume of SO2

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4

If all the octahedral sites in a cubic close packed arrangement (B-) are completelyfilled with A+ cations, the empirical formula of the compound could then be

A. AB2

B. A2B

C. AB

D. None of these

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4

Four 1 litre flasks are separately filled with the gases hydrogen, helium, oxygen and ozone at the same temperature and pressure, the ratio of total number of atoms of these gases present in the different flasks would be

A. 3:2:2:1

B. 2:1:2:3

C. 1:2:2:3

D. 1:1:1:1

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4

The molecular weight of a volatile liquid can be determined by

A. Dumas' method

B. Victor Meyer's method

C. Cryoscopic method

D. Osmotic pressure

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4

At what temperature, the root mean square velocity of oxygen molecules is equal to that of SO2 at 27°C?

A. 150°C

B. 150°K

C. 27°C

D. None of these

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4

Which one of the following contains same number of molecules as 4.4 gm of carbon dioxide (mol. wt. of CO2 = 44, Mol, wt. of SO2 = 64)?

A. 64 gm of sulphur dioxide

B. 4.4 gm of sulphur dioxide

C. 6.4 gm of sulphur dioxide

D. 3.2 gm of sulphur dioxide

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4

Molecular formula of D in the above case is

A. AB5

B. A5B2  

C. A2B5 

D. AB

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4

The vapour density of completely dissociated sociated NH4CL would be

A. Determined by the amount of solid NH4CL used in the experiment

B. Triple to that of NH4CL

C. Half of that NH4CL

D. Slightly less than half of that of NH4CL

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4

22.4 litres of SO2 at 27.3°C and 1 atmosphere pressure shall weigh

A. 32 g

B. 16 g

C. 44.8 g

D. 48.5 g

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4

Normal boiling points values are for NH3, - 34C, bromine 58°C, carbon tetrachloride 77°C and oxygen - 183°C. Which of these liquids has the highest vapour pressure at room temperature?

A. NH3,

B. Br2

C. CCl4

D. O2

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4

Gases deviate from the ideal behaviour because their molecules

A. possess negligible volume

B. have forces of attraction between them

C. are polyatomic

D. are not attracted to one another

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4

At 303 K ethanol has a vapour pressure of about 0.118 atm., acetic acid has the vapour pressure of about 0.039 atm., and ethyl iodide has a vapour pressure of about 0.263 atm. Which of the following represents the correct order of increasing normal boiling point ?

A. CH3COOH<C2H5OH<C2H5I

B. C2H5I<CH3COOH<C2H5OH

C. C2H5I<C2H5OH<CH3COOH

D. C2H5OH<C2H5I<CH3COOH