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The Van der Waal's equation explains the behaviour of
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The radii of and are 95 pm and 181 pm respectively. Coordination number of is expected to be
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Indicate the most viscous liquid of the following
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The weight of 11.2 litres of at S.T.P. would be
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The limiting radii ratio for the tetrahedral geometry is
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What is the vapour pressure of benzoyl chloride at its boiling point (197°C)?
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The ionic radii of and are 0.66 and 1.40 , respectively. The most probable type of gteometry exhibited by MgO on the basis of radius ratio rule is
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Which of the following contains the same number of atoms as 12 gms: of Magnesium (Atomic weights : Mg = 24, C = 12, Ca = 40)
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Match box has the symmetry of which of the following systems?
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The V.D. of a gas is 11.2 gm. The volume occupied by 11.2 gm. of this gas at N.T.P. is
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Arrange the following in order of increasing inter-molecular forces and boiling points:,He,
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In NaCl type structure, the coordination number of the cation and anion are
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Of the following properties, the magnitude of one must always increase with temperature. The property is
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The number of N2 molecules present in 28 nitrogen is
C. 6 x approximately
D. 5 x approximately
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Which of the following is an amorphous solid?
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When there is more deviation in the behaviour of a gas from ideal gas equation PV = nRT
A. at high temperature and low pressure
B. at low temperature and high pressure
C. at high temperature and high pressure
D. at low temperature and low pressure
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4
Indicate the most volatile liquid of the following:
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The vapour density of a gas is 11.2. The volume occupied by 2.4 g of the gas at S.T.P wil be
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If the temperature and pressure remain unchanged the volume of obtained by the decomposition of a certain volume of will be
A. Triple the volume of
B. Half the volume of
C. Equal to the volume of
D. One third the volume of
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If all the octahedral sites in a cubic close packed arrangement () are completelyfilled with cations, the empirical formula of the compound could then be
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Four 1 litre flasks are separately filled with the gases hydrogen, helium, oxygen and ozone at the same temperature and pressure, the ratio of total number of atoms of these gases present in the different flasks would be
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The molecular weight of a volatile liquid can be determined by
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At what temperature, the root mean square velocity of oxygen molecules is equal to that of at 27°C?
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Which one of the following contains same number of molecules as 4.4 gm of carbon dioxide (mol. wt. of = 44, Mol, wt. of = 64)?
A. 64 gm of sulphur dioxide
B. 4.4 gm of sulphur dioxide
C. 6.4 gm of sulphur dioxide
D. 3.2 gm of sulphur dioxide
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Molecular formula of D in the above case is
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The vapour density of completely dissociated sociated would be
A. Determined by the amount of solid used in the experiment
B. Triple to that of
D. Slightly less than half of that of
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4
22.4 litres of at 27.3°C and 1 atmosphere pressure shall weigh
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Normal boiling points values are for , - 34C, bromine 58°C, carbon tetrachloride 77°C and oxygen - 183°C. Which of these liquids has the highest vapour pressure at room temperature?
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4
Gases deviate from the ideal behaviour because their molecules
A. possess negligible volume
B. have forces of attraction between them
D. are not attracted to one another
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At 303 K ethanol has a vapour pressure of about 0.118 atm., acetic acid has the vapour pressure of about 0.039 atm., and ethyl iodide has a vapour pressure of about 0.263 atm. Which of the following represents the correct order of increasing normal boiling point ?