Related Questions
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4
Work done may be calculated by the expression ∫ p dA for __________ processes.
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Pick out the wrong statement.
A. An ideal liquid or solid solution is defined as one in which each component obeys Raoult's law
B. If Raoult's law is applied to one component of a binary mixture; Henry's law or Raoult's law is applied to the other component also
C. Henry's law is rigorously correct in the limit of infinite dilution
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4
In the reaction, C + O2 → CO2; ΔH = - 94 kcal. What is the heat content (enthalpy) of O2?
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Steam undergoes isentropic expansion in a turbine from 5000 kPa and 400°C (entropy = 6.65 kJ/kg K) to 150 kPa) (entropy of saturated liquid = 1.4336 kJ/kg. K, entropy of saturated vapour = 7.2234 kJ/kg. K) The exit condition of steam is
B. Partially condensed vapour with quality of 0.9
D. Partially condensed vapour with quality of 0.1
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4
In case of the decomposition of hydroiodic acid (2HI H2 + I2), addition of H2 (at equilibrium condition) will
A. Increase the partial pressure of I2
B. Decrease the partial pressure of HI
C. Diminish the degree of dissociation of HI
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Isentropic process means a constant __________ process.
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Heat of formation of an element in its standard state is
D. A function of pressure
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Free energy changes for two reaction mechanism 'X' and 'Y are respectively - 15 and - 5 units. It implies that X is
C. Three times slower than Y
D. Three times faster than Y
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Maxwell's relation corresponding to the identity, dH = dS = Vdp + Σμi dni is
A. (∂T/∂V)S, ni = -(∂P/∂S)V, ni
B. (∂S/∂P)T, ni = (∂V/∂T)P, ni
C. (∂S/∂V)T, ni = (∂P/∂T)V, ni
D. (∂T/∂P)S, ni = (∂V/∂S)P, ni
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Refrigeration capacity of a household refrigerator may be round about __________ tons.
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The work done in an adiabatic change in a particular gas depends upon changes in the __________ only.
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In the decomposition of PCl5 represented by, PCl5 PCl3 + Cl2, decrease in the pressure of the system will __________ the degree of dissociation of PCl5.
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The internal energy of an incompressible fluid depends upon its
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When liquid and vapour phase of multi-component system are in equilibrium (at a given temperature and pressure), then chemical potential of each component is
A. Same in both the phases
B. Zero in both the phases
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On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)s and the slope of the reversible isothermal line (∂P/ ∂V)T are related as (where, y = Cp/Cv)
B. (∂P/∂V)S = [(∂P/∂V)T]Y
D. (∂P/∂V)S = 1/y(∂P/∂V)T
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Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure.
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The temperature at which both liquid and gas phases are identical, is called the __________ point.
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In the equation, PVn = constant, if the value of n = 1, then it represents a reversible __________ process.
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4
In an ideal solution, the activity of a component equals its
B. Fugacity at the same temperature and pressure
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A cylinder contains 640 gm of liquid oxygen. The volume occupied (in litres) by the oxygen, when it is released and brought to standard conditions (0°C, 760 mm Hg) will be __________ litres.
D. Data insufficient; can't be computed
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Work done in an adiabatic process between two states depends on the
A. Rate of heat transmission
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Adiabatic compression of a saturated water vapour makes it
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In a working refrigerator, the value of COP is always
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A system in which there is exchange of energy but not of mass, is called a/an __________ system.
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For any system, what is the minimum number of degrees of freedom?
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A large iceberg melts at the base, but not at the top, because of the reason that
A. Ice at the base contains impurities which lowers its melting point
B. Due to the high pressure at the base, its melting point reduces
C. The iceberg remains in a warmer condition at the base
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4
In the reaction, H2 +I2 2HI, addition of an inert gas will
A. Increase the partial pressure of H2
B. Increase the partial pressure of I2
C. Increase the total pressure and hence shift the equilibrium towards the right
D. Not affect the equilibrium conditions
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Solid and liquid phases of a substance are in equilibrium at the
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If different processes are used to bring about the same chemical reaction, the enthalpy change is same for all of them. This is __________ law.
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Helmholtz free energy (A) is defined as