Isochoric
Isobaric
Adiabatic
Isothermal
B. Isobaric
The amount of work needed is path dependent
Work alone cannot bring out such a change of state
The amount of work needed is independent of path
More information is needed to conclude anything about the path dependence or otherwise of the work needed
Not a function of its pressure
Not a function of its nature
Not a function of its temperature
Unity, if it follows PV = nRT
μ° + RT ln f
μ°+ R ln f
μ° + T ln f
μ° + R/T ln f
Pressure
Volume
Temperature
All (A), (B) & (C)
Volume of the liquid phase is negligible compared to that of vapour phase
Vapour phase behaves as an ideal gas
Heat of vaporisation is independent of temperature
All (A), (B) & (C)
Kp2/Kp1 = - (ΔH/R) (1/T2 - 1/T1)
Kp2/Kp1 = (ΔH/R) (1/T2 - 1/T1)
Kp2/Kp1 = ΔH (1/T2 - 1/T1)
Kp2/Kp1 = - (1/R) (1/T2 - 1/T1)
Work required to refrigeration obtained
Refrigeration obtained to the work required
Lower to higher temperature
Higher to lower temperature
Pressure
Composition
Temperature
All (A), (B) and (C)
Only enthalpy change (ΔH) is negative
Only internal energy change (ΔE) is negative
Both ΔH and ΔE are negative
Enthalpy change is zero
Cp < Cv
Cp = Cv
Cp > Cv
C ≥ Cv
A heating effect
No change in temperature
A cooling effect
Either (A) or (C)
With pressure changes at constant temperature
Under reversible isothermal volume change
During heating of an ideal gas
During cooling of an ideal gas
Lowest
Highest
Average
None of these
Molecular size
Volume
Pressure
Temperature
TR/(T2 - TR) × (T1 - T2)/T1
TR/(T2 - TR) × T1/(T1 - T2)
TR/(T1 - TR) × (T1 - T2)/T1
None of these
35 K
174 K
274 K
154 K
The statement as per Gibbs-Helmholtz
Called Lewis-Randall rule
Henry's law
None of these
Isothermally
Isobarically
Adiabatically
None of these
0
> 0
< 0
None of these
Decrease in temperature
Increase in temperature
No change in temperature
Change in temperature which is a function of composition
A refrigeration cycle violates the second law of thermodynamics
Refrigeration cycle is normally represented by a temperature vs. entropy plot
In a refrigerator, work required decreases as the temperature of the refrigerator and the temperature at which heat is rejected increases
One ton of refrigeration is equivalent to the rate of heat absorption equal to 3.53 kW
Decreases in all spontaneous (or irreversible) processes
Change during a spontaneous process has a negative value
Remains unchanged in reversible processes carried at constant temperature and pressure
All (A), (B) and (C)
Freon-12
Ethylene
Ammonia
Carbon dioxide
0.15
1.5
4.5
6.5
Infinity
Unity
Constant
Negative
At constant pressure, solubility of a gas in a liquid diminishes with rise in temperature
Normally, the gases which are easily liquefied are more soluble in common solvents
The gases which are capable of forming ions in aqueous solution are much more soluble in water than in other solvents
At constant pressure, solubility of a gas in a liquid increases with rise in temperature
Zero
Unity
Infinity
An indeterminate value
Chemical potentials of a given component should be equal in all phases
Chemical potentials of all components should be same in a particular phase
Sum of the chemical potentials of any given component in all the phases should be the same
None of these
Is the most efficient of all refrigeration cycles
Has very low efficiency
Requires relatively large quantities of air to achieve a significant amount of refrigeration
Both (B) and (C)
Concentration of the constituents only
Quantities of the constituents only
Temperature only
All (A), (B) and (C)