Related Questions
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4
Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 PCl3 + Cl2.Degree of dissociation of PCl5 will
A. Decrease on addition of Cl2
B. Increase on addition of an inert gas at constant pressure
C. Decrease on increasing the pressure of the system
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4
PVy = constant, holds good for an isentropic process, which is
A. Reversible and isothermal
B. Isothermal and irreversible
C. Reversible and adiabatic
D. Adiabatic and irreversible
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4
Which of the following is affected by the temperature?
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4
Entropy of an ideal gas depends upon its
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4
What is the degree of freedom for a system comprising liquid water equilibrium with its vapour?
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4
The equation, Cp - Cv = R, is true for __________ gas.
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(∂H/∂T)P is the mathematical expression for
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The work done in an adiabatic change in a particular gas depends upon changes in the __________ only.
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The enthalpy change when ammonia gas is dissolved in water is called the heat of
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Heat evolved/absorbed during conversion of a substance from one allotropic form to another is termed as the heat of
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4
For a single component two phase mixture, the number of independent variable properties are
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Pick out the correct statement:
A. In an isothermal system, irreversible work is more than reversible work
B. Under reversible conditions, the adiabatic work is less than isothermal work
C. Heat, work, enthalpy and entropy are all 'state functions'
D. Matter and energy cannot be exchanged with the surroundings in a closed system
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4
Clapeyron Equation deals with the
A. Rate of change of vapour pressure with temperature
B. Effect of an inert gas on vapour pressure
C. Calculation of ΔF for spontaneous phase change
D. Temperature dependence of heat of phase transition
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4
Degree of freedom of a system consisting of a gaseous mixture of H2 and NH3 will be
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A gas mixture of three components is brought in contact with a dispersion of an organic phase in water. The degree of freedom of the system is
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A system undergoes a change from a given initial state to a given final state either by an irreversible process or by a reversible process, then (where, Δ S1 and Δ SR are the entropy changes of the system for the irreversible and reversible processes respectively)
B. Δ S1 is sometimes > Δ SR
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4
The expression for entropy change given by, ΔS = - nR ln (P2/P1), holds good for
A. Expansion of a real gas
B. Reversible isothermal volume change
C. Heating of an ideal gas
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4
If the pressure on 100 c.c. of air is halved, then its volume (at the same temperature) would be __________ c.c.
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4
Co-efficient of Performance (COP) of a refrigerator is the ratio of the
A. Work required to refrigeration obtained
B. Refrigeration obtained to the work required
C. Lower to higher temperature
D. Higher to lower temperature
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4
On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)s and the slope of the reversible isothermal line (∂P/ ∂V)T are related as (where, y = Cp/Cv)
B. (∂P/∂V)S = [(∂P/∂V)T]Y
D. (∂P/∂V)S = 1/y(∂P/∂V)T
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A cyclic engine exchanges heat with two reservoirs maintained at 100 and 300°C respectively. The maximum work (in J) that can be obtained from 1000 J of heat extracted from the hot reservoir is
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4
Chemical potential of ith component of a system is given by
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To obtain integrated form of Clausius-Clapeyron equation, ln (P2/P1) = (ΔHV/R) (1/T1 - 1/T2) from the exact Clapeyron equation, it is assumed that the
A. Volume of the liquid phase is negligible compared to that of vapour phase
B. Vapour phase behaves as an ideal gas
C. Heat of vaporisation is independent of temperature
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For any system, what is the minimum number of degrees of freedom?
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Joule-Thomson co-efficient depends on the
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In case of vapour compression refrigeration system, elevating the evaporator temperature (keeping the condenser temperature constant) results in
C. No change in the value of COP
D. Increased or decreased COP; depending upon the type of refrigerant
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4
Chemical potential is a/an
C. Force which drives the chemical system to equilibrium
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Pick out the wrong statement.
A. Minimum number of degree of freedom of a system is zero
B. Degree of freedom of a system containing a gaseous mixture of helium, carbon dioxide and hydrogen is 4
C. For a two phase system in equilibrium made up of four non-reacting chemical species, the number of degrees of freedom is 4
D. Enthalpy and internal energy change is zero during phase change processes like melting, vaporisation and sublimation
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4
A cylinder contains 640 gm of liquid oxygen. The volume occupied (in litres) by the oxygen, when it is released and brought to standard conditions (0°C, 760 mm Hg) will be __________ litres.
D. Data insufficient; can't be computed
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Efficiency of a Carnot engine working between temperatures T1 and T2 (T1 < T) is