Related Questions
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Lenz's law results from the law of conservation of
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What is the degree of freedom for two miscible (non-reacting) substances in vapor-liquid equilibrium forming an azeotrope?
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4
After throttling, gas temperature
D. May increase or decrease; depends on the nature of the gas
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4
Solid and liquid phases of a substance are in equilibrium at the
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Which of the following equations is obtained on combining 1st and 2nd law of thermodynamics, for a system of constant mass?
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Two substances are in equilibrium in a reversible chemical reaction. If the concentration of each substance is doubled, then the value of the equilibrium constant will be
D. One fourth of its original value
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In case of a reversible process (following pvn = constant), work obtained for trebling the volume (v1 = 1 m3 and v23 m3) is maximum, when the value of 'n' is
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Forward reaction will be favoured for the exothermic reaction, represented by CO + H2O CO2 + H2, by
A. Low temperature and high pressure
B. Low temperature and low pressure
C. High temperature and high pressure
D. High temperature and low pressure
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4
The specific heat of saturated water vapour at 100°C is
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Joule-Thomson co-efficient is defined as
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Heat of formation of an element in its standard state is
D. A function of pressure
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Entropy of an ideal gas depends upon its
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Pick out the extensive property out of the following.
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Entropy change in case of reversible adiabatic process is
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An irreversible process
A. Is the analog of linear frictionless motion in machines
B. Is an idealised visualisation of behaviour of a system
C. Yields the maximum amount of work
D. Yields an amount of work less than that of a reversible process
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One mole of nitrogen at 8 bar and 600 K is contained in a piston-cylinder arrangement. It is brought to 1 bar isothermally against a resisting pressure of 1 bar. The work done (in Joules) by the gas is
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The ammonia synthesis reaction represented by N2 + 3H2 2NH3; ΔH = - 22.4 kcal, is
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For the gaseous phase chemical reaction, C2H4(g) + H2O(g) ↔ C2H5OH(g), the equilibrium conversion does not depend on the
A. Steam to ethylene ratio
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High __________ is an undesirable property for a good refrigerant.
B. Latent heat of vaporisation
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__________ increases with increase in pressure.
A. The melting point of wax
B. The boiling point of a liquid
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Which of the following has the minimum value of COP for a given refrigeration effect?
B. Ordinary vapour-compression cycle
C. Vapour-compression process with a reversible expansion engine
D. Air refrigeration cycle
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Joule-Thomson co-efficient which is defined as, η = (∂T/∂P)H = 1/Cp (∂H/∂T)P, changes sign at a temperature known as inversion temperature. The value of Joule-Thomson co-efficient at inversion temperature is
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4
Fugacity is a measure of the
A. Escaping tendencies of the same substance in different phases of a system
B. Relative volatility of a mixture of two miscible liquids
C. Behaviour of ideal gases
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For multi-component multiple phases to be in equilibrium at the same pressure and temperature, the __________ of each component must be same in all phases.
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Isobaric process means a constant process.
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The temperature at which a real gas obeys the ideal gas laws over a wide range of pressure is called the __________ temperature.
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Boiling of liquid is accompanied with increase in the
B. Specific Gibbs free energy
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For a reversible process involving only pressure-volume work
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Work done in case of free expansion is
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In the reaction, represented by, 2SO2 + O2 2SO3; ΔH = - 42 kcal; the forward reaction will be favoured by