Related Questions
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All gases except __________ shows a cooling effect during throttling process at atmospheric temperature and pressure.
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A chemical reaction will occur spontaneously at constant pressure and temperature, if the free energy is
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The standard Gibbs free energy change of a reaction depends on the equilibrium
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Heat pump
A. Accomplishes only space heating in winter
B. Accomplishes only space cooling in summer
C. Accomplishes both (A) and (B)
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dW and dq are not the exact differential, because q and W are
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One mole of nitrogen at 8 bar and 600 K is contained in a piston-cylinder arrangement. It is brought to 1 bar isothermally against a resisting pressure of 1 bar. The work done (in Joules) by the gas is
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Degrees of freedom at triple point will be
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For a real gas, the chemical potential is given by
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What is the value of maximum COP in case of absorption refrigeration, if refrigeration provided is at temperature, TR (where, T1 and T2 are source & surrounding temperatures respectively.)?
A. TR/(T2 - TR) × (T1 - T2)/T1
B. TR/(T2 - TR) × T1/(T1 - T2)
C. TR/(T1 - TR) × (T1 - T2)/T1
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Mollier chart is a __________ plot.
D. Temperature vs. entropy
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The equilibrium constant for a chemical reaction at two different temperatures is given by
A. Kp2/Kp1 = - (ΔH/R) (1/T2 - 1/T1)
B. Kp2/Kp1 = (ΔH/R) (1/T2 - 1/T1)
C. Kp2/Kp1 = ΔH (1/T2 - 1/T1)
D. Kp2/Kp1 = - (1/R) (1/T2 - 1/T1)
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An isentropic process is carried out at constant
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A system is said to be at equilibrium, if the entropy of the system has reached __________ value.
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In case of an __________ process, the temperature of the system increases.
A. Isothermal compression
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1st law of thermodynamics is nothing but the law of conservation of
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Compressibility factor (i.e., the ratio of actual volume of gas to the volume predicted by ideal gas law) for all gases are
A. Always greater than one
B. Same at the same reduced temperature
C. Same at the same reduced pressure
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A cyclic engine exchanges heat with two reservoirs maintained at 100 and 300°C respectively. The maximum work (in J) that can be obtained from 1000 J of heat extracted from the hot reservoir is
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Mollier diagram is a plot of
A. Temperature vs. enthalpy
B. Temperature vs. enthalpy
D. Temperature vs. internal energy
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__________ does not change during phase transformation processes like sublimation, melting & vaporisation.
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In Joule-Thomson porous plug experiment, the
A. Enthalpy does not remain constant
B. Entire apparatus is exposed to surroundings
C. Temperature remains constant
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Which of the following is not affected by temperature changes?
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4 kg moles of an ideal gas expands in vacuum spontaneously. The work done is
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The unit of equilibrium constant of a chemical reaction is the same as that of
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The energy of activation of exothermic reaction is
C. Very large compared to that for endothermic reaction
D. Not possible to predict
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The heat capacities for the ideal gas state depend upon the
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Isentropic process means a constant __________ process.
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Pick out the wrong statement.
A. Activity co-efficient is dimensionless.
B. In case of an ideal gas, the fugacity is equal to its pressure.
C. In a mixture of ideal gases, the fugacity of a component is equal to the partial pressure of the component.
D. The fugacity co-efficient is zero for an ideal gas
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In case of the decomposition of hydroiodic acid (2HI H2 + I2), addition of H2 (at equilibrium condition) will
A. Increase the partial pressure of I2
B. Decrease the partial pressure of HI
C. Diminish the degree of dissociation of HI
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The equation relating E, P, V and T which is true for all substances under all conditions is given by (∂E/∂V)T = T(∂P/∂T)H - P. This equation is called the
B. Thermodynamic equation of state
D. Redlich-Kwong equation of state
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Fugacity co-efficient of a substance is the ratio of its fugacity to