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What is the correct answer?

4

In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is

A. More

B. Less

C. Same

D. Unpredictable; depends on the particular reaction

Correct Answer :

C. Same


Related Questions

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4

If two gases have same reduced temperature and reduced pressure, then they will have the same

A. Volume

B. Mass

C. Critical temperature

D. None of these

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4

The expression, nCv(T2 - T1), is for the __________ of an ideal gas.

A. Work done under adiabatic condition

B. Co-efficient of thermal expansion

C. Compressibility

D. None of these

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4

In the equation, PVn = Constant, if the value of n = 0, then it represents a reversible __________ process.

A. Isobaric

B. Isothermal

C. Isentropic

D. Isometric

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4

Compressibility factor of a gas is

A. Not a function of its pressure

B. Not a function of its nature

C. Not a function of its temperature

D. Unity, if it follows PV = nRT

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4

(∂H/∂T)P is the mathematical expression for

A. CV

B. Entropy change

C. Gibbs free energy

D. None of these

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4

For a given substance at a specified temperature, activity is __________ to fugacity.

A. Directly proportional

B. Inversely proportional

C. Equal

D. None of these

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4

Air enters an adiabatic compressor at 300K. The exit temperature for a compression ratio of 3, assuming air to be an ideal gas (Y = Cp/Cv = 7/5) and the process to be reversible, is

A. 300 × (32/7)

B. 300 × (33/5)

C. 300 × (333/7)

D. 300 × (35/7)

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4

Gibbs free energy of mixing at constant pressure and temperature is always

A. 0

B.

C. + ve

D. - ve

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4

Clausius-Clapeyron equation is applicable to __________ equilibrium processes.

A. Solid-vapor

B. Solid-liquid

C. Liquid-vapor

D. All (A), (B) and (C)

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4

The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv), depends upon its

A. Pressure

B. Volume

C. Temperature

D. All (A), (B) & (C)

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4

Equilibrium constant decreases as the temperature

A. Increases, for an exothermic reaction

B. Decreases, for an exothermic reaction

C. Increases, for an endothermic reaction

D. None of these

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4

Gibbs phase rule finds application, when heat transfer occurs by

A. Conduction

B. Convection

C. Radiation

D. Condensation

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4

Pick out the correct statement.

A. Compression ratio of an Otto engine is comparatively higher than a diesel engine

B. Efficiency of an Otto engine is higher than that of a diesel engine for the same compression ratio

C. Otto engine efficiency decreases with the rise in compression ratio, due to decrease in work produced per quantity of heat

D. Diesel engine normally operates at lower compression ratio than an Otto engine for an equal output of work

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4

Enthalpy of a gas depends upon its

A. Temperature

B. Mass

C. Volume

D. Pressure

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4

In the equation, PVn = constant, if the value of n is in between 1 and y (i.e. Cp/Cv), then it represents a reversible __________ process.

A. Isometric

B. Polytropic

C. Isentropic

D. Isobaric

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4

Pick out the correct statement.

A. Like internal energy and enthalpy, the absolute value of standard entropy for elementary substances is zero

B. Melting of ice involves increase in enthalpy and a decrease in randomness

C. The internal energy of an ideal gas depends only on its pressure

D. Maximum work is done under reversible conditions

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4

For a single component two phase mixture, the number of independent variable properties are

A. Two

B. One

C. Zero

D. Three

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4

Fugacity is most helpful in

A. Representing actual behaviour of real gases

B. Representing actual behaviour of ideal gases

C. The study of chemical equilibria involving gases at atmospheric pressure

D. None of these

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4

__________ calorimeter is normally used for measuring the dryness fraction of steam, when it is very low.

A. Bucket

B. Throttling

C. Separating

D. A combination of separating & throttling

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4

The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and pressure. It is given by

A. (∂E/∂ni)S, v, nj

B. (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj

C. (∂H/∂ni)S, P, nj

D. All (A), (B) and (C)

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4

After throttling, gas temperature

A. Decreases

B. Increases

C. Remain same

D. May increase or decrease; depends on the nature of the gas

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4

Fugacity of a component in an ideal gas mixture is equal to the partial pressure of that component in the mixture. The fugacity of each component in a stable homogeneous solution at constant pressure and temperature __________ as its mole fraction increases.

A. Decreases

B. Decreases exponentially

C. Increases

D. Remain constant

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4

For spontaneous changes in an isolated system (S = entropy)

A. ds = 0

B. ds <0

C. ds > 0

D. ds = Constant

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4

The equation, Cp - Cv = R, is true for __________ gas.

A. No

B. Any real

C. Only ideal

D. Both (B) and (C)

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4

All gases above its inversion temperature, in a throttling process will show

A. A heating effect

B. No change in temperature

C. A cooling effect

D. Either (A) or (C)

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4

Normal temperature and pressure (N.T.P.) corresponds to

A. 0°C and 760 mm Hg

B. 15°C and 760 mm Hg

C. 20°C and 760 mm Hg

D. 0°C and 1 kgf/cm2

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4

In the reaction, C + O2 → CO2; ΔH = - 94 kcal. What is the heat content (enthalpy) of O2?

A. -94 kcal

B. > -94 kcal

C. < - 94 kcal

D. Zero

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4

Pick out the wrong statement.

A. The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction

B. With increase in temperature, the equilibrium constant increases for an exothermic reaction

C. The equilibrium constant of a reaction depends upon temperature only

D. The conversion for a gas phase reaction increases with increase in pressure, if there is a decrease in volume accompanying the reaction

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4

Specific heat of a gas for a reversible adiabatic process is

A. Negative

B. Zero

C. Infinity

D. None of these

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4

The standard state of a gas (at a given temperature) is the state in which fugacity is equal to

A. Unity

B. Activity

C. Both (A) & (B)

D. Neither (A) nor (B)