Related Questions
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Critical temperature is defined as the temperature above which a gas will
A. Not liquify (barring exceptions)
C. Never liquify however high the pressure may be
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If different processes are used to bring about the same chemical reaction, the enthalpy change is same for all of them. This is __________ law.
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Critical solution temperature (or the consolute temperature) for partially miscible liquids (e.g., phenol-water) is the minimum temperature at which
A. A homogeneous solution (say of phenol water) is formed
B. Mutual solubility of the two liquids shows a decreasing trend
C. Two liquids are completely separated into two layers
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In any spontaneous process,
C. Both F and A decreases
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Compressibility factor (i.e., the ratio of actual volume of gas to the volume predicted by ideal gas law) for all gases are
A. Always greater than one
B. Same at the same reduced temperature
C. Same at the same reduced pressure
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Third law of thermodynamics is helpful in
A. Prediction of the extent of a chemical reaction
B. Calculating absolute entropies of substances at different temperature
C. Evaluating entropy changes of chemical reaction
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All gases except __________ shows a cooling effect during throttling process at atmospheric temperature and pressure.
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The co-efficient of performance (COP) of a refrigerating system, which is its index of performance, is defined as the ratio of useful refrigeration to the net work. The units of __________ and COP are the same.
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The point at which all the three (solid, liquid and gas) phases co-exist, is known as the __________ point.
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In the equation, PVn = constant, if the value of n is in between 1 and y (i.e. Cp/Cv), then it represents a reversible __________ process.
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In case of a reversible process (following pvn = constant), work obtained for trebling the volume (v1 = 1 m3 and v23 m3) is maximum, when the value of 'n' is
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At a given temperature, the volume of a gas dissolved in a solvent __________ with increase in pressure.
D. May increase or decrease; depends on the gas
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Joule-Thomson co-efficient for a perfect gas is
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An ideal monatomic gas is taken round the cycle ABCDA as shown below in the P-V diagram. The work done during the cycle is
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A large iceberg melts at the base, but not at the top, because of the reason that
A. Ice at the base contains impurities which lowers its melting point
B. Due to the high pressure at the base, its melting point reduces
C. The iceberg remains in a warmer condition at the base
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The most important application of distribution law is in
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Pick out the wrong statement.
A. Trouton's ratio of non-polar liquids is calculated using Kistyakowsky equation
B. Thermal efficiency of a Carnot engine is always less than 1
C. An equation relating pressure, volume and temperature of a gas is called ideal gas equation
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The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv), depends upon its
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In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is
D. Unpredictable; depends on the particular reaction
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At equilibrium condition, the chemical potential of a material in different phases in contact with each other is equal. The chemical potential for a real gas (μ) is given by (where, μ = standard chemical potential at unit fugacity (f° = 1 atm.) and the gas behaves ideally.)
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Melting of wax is accompanied with __________ in entropy.
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A Carnot cycle consists of the following steps:
A. Two isothermal and two isentropic
B. Two isobaric and two isothermal
C. Two isochoric and two isobaric
D. Two isothermals and two isochoric
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Keeping the pressure constant, to double the volume of a given mass of an ideal gas at 27°C, the temperature should be raised to __________ °C.
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(∂E/∂T)V is the mathematical expression for
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In polytropic process (PVn = constant), if n = 1; it means a/an __________ process.
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For a constant volume process __________ by the system is used only to increase the internal energy.
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Heat is added at constant pressure in an ideal __________ cycle.
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In a working refrigerator, the value of COP is always
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Boiling of liquid is accompanied with increase in the
B. Specific Gibbs free energy
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__________ decreases during adiabatic throttling of a perfect gas.