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4

Lattice energy of a solid is high if

A. the radii of the ions are large

B. radii of the ions are small

C. charge on the ions are small

D. the ions are neutral

Correct Answer :

B. radii of the ions are small


Related Questions

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4

In which one of the following does diffusion occur most rapidly?

A. Solid

B. Liquid

C. Gases

D. Gels

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4

The temperature at which a real gas obeys the ideal gas laws over a wide range of pressure:

A. critical temperature

B. Boyle's temperature

C. inversion temperature

D. reduced temperature

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4

The ionic radii of Rb+ and Br- ions are 1.47 A° and 1.95 A°, respectively. The most probable type of geometry exhibited by RbBr on the radius ratio rule is

A. NaCl type

B. CsCl type

C. Zinc blende structure

D. Wurtzite structure

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4

The mean free path of a gas molecule is the distance

A. between the two opposite walls of the container

B. through which the molecules travel in one second

C. through which molecules move between two consecutive collisions

D. travelled by all the molecules divided by the total number of molecules in a particular gas

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4

A gas or vapour may be liquefied only at a temperature at or

A. below the critical temperature

B. above the critical temperature

C. above the normal boiling point

D. at any temperature

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4

Density of a gas relative to air is 2.3. If the average molar mass of air is 29.08/mol, the molecular mass of the gas will be

A. 29 gm/mole

B. 66.7 gm/mole

C. 12.67 gm/mole

D. 25.22 gm/mole

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4

The molecular velocity of any gas is

A. proportional to absolute temperature

B. proportional to the square root of absolute temperature

C. independent of temperature

D. proportional to die square of absolute temperature

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4

The kinetic theory of gases predicts that total kinetic energy of a gaseous assembly depends upon the

A. pressure of a gas

B. temperature of the gas

C. volume of the gas

D. pressure, temperature and volume of the gas

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4

Chloroform and benzene form a pair of miscible liquids. These can be separated by

A. a separating funnel

B. distillation

C. sublimation

D. filtration

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4

At 303 K ethanol has a vapour pressure of about 0.118 atm., acetic acid has the vapour pressure of about 0.039 atm., and ethyl iodide has a vapour pressure of about 0.263 atm. Which of the following represents the correct order of increasing normal boiling point ?

A. CH3COOH<C2H5OH<C2H5I

B. C2H5I<CH3COOH<C2H5OH

C. C2H5I<C2H5OH<CH3COOH

D. C2H5OH<C2H5I<CH3COOH

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4

The vapour density of completely dissociated sociated NH4CL would be

A. Determined by the amount of solid NH4CL used in the experiment

B. Triple to that of NH4CL

C. Half of that NH4CL

D. Slightly less than half of that of NH4CL

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4

Lattice energy of a solid is high if

A. the radii of the ions are large

B. radii of the ions are small

C. charge on the ions are small

D. the ions are neutral

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4

The number of atoms in 0.004 gm of magnesium is close to

A. 36x   105

B.  1020

C. 5 x  1020

D. 6.02 x 1023

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4

5.At a given temperature and pressure 2 volumes of A combine with 5 volumes of B to form 2 volmes of C and 1 volume. A combine with one volume of B to form 2 volumes of D. The formula of C is

A. A3B6

B. AB

C. A2B5

D. AB5

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4

A vessel containing 10 litre of air at atmospheric pressure is connected to an evacuated 9 litre vessel The resulting pressure will be

A. 2 atm

B. 31 atm

C. 0.526 atm

D. 52.6 atm

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4

In a close packed arrangement of N spheres, the number of octahedral holes are

A. N

B. 2N

C. 4N

D. 8N

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4

The best electrical conductor of the following is

A. CO2(s)

B. Si(s)

C. NaCl (fused)

D. Br2(I)

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4

Normal boiling points values are for NH3, - 34C, bromine 58°C, carbon tetrachloride 77°C and oxygen - 183°C. Which of these liquids has the highest vapour pressure at room temperature?

A. NH3,

B. Br2

C. CCl4

D. O2

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4

Four 1 litre flasks are separately filled with hydrogen, helium, oxygen and ozone gases at the same temperature and pressure. The ratio of total number of atoms of these gases present in the different flasks would be

A. 1:1:1:1

B. 1:2:2:3

C. 2:1:2:3

D. 3:2:2:1

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4

In the ideal gas equation PV = nRT constant 'R' has the unit

A. joule

B. litre/mol

C. lit-atm/deg/mol

D. calorie/mole

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4

In NaCl type structure, the coordination number of the cation and anion are

A. 6 and 4

B. 6 and 6

C. 4 and 4

D. 8 and 4

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4

Indicate the most volatile liquid of the following:

A. CH3OH

B. CH3OCH3

C.  H2O

D. CH3CH2OCH2CH3

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4

Indicate the most viscous liquid of the following

A. propanol-2

B. 1.2, ethandiol

C. 1.2,3 propentriol

D. ethanol

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4

What is the vapour pressure of benzoyl chloride at its boiling point (197°C)?

A. 760 torr

B. 380 torr

C. 197 torr

D. None of these

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4

Which of the following contains the same number of atoms as 12 gms: of Magnesium (Atomic weights : Mg = 24, C = 12, Ca = 40)

A. 10 gms of calcium

B. 20 gms of carbon

C. 20 gms of calcium

D. 12 gms of carbon

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4

Kinetic theory of gases postulates :

A. The molecules in a gas are in stationary state

B. The molecules in a gas exert appreciable attraction on each other

C. The molecules move in a random motion with widely different velocities

D. The molecules in a gas collide against each other as well as the wall of the container, but do not change their direction of motion

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4

Absolute zero is the temperature at which

A. water freezes

B. all gases become liquid

C. all substances are solid

D. molecular motion ceases

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4

In zinc blende structure, the zinc atoms occupy

A. all tetrahedral sites

B. all octahedral sites

C. half of the octahedral sites

D. half of the tetrahedral sites

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4

Number of molecules of carbon dioxide present in 44 gm CO2 is

A. 12 x 1023 approximately

B. 3 x  1010 approximately

C. 6 x  1010 approximately

D. 3 x 1023 approximately

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4

How many moles of water are present in 180 gm. of water ?

A. 11

B. 5

C. 90

D. 21