Related Questions
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Heat requirement for decomposition of a compound into its elements is __________ that is evolved during the formation of that compound from its elements.
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If we increase the pressure on a substance (which is at its triple point), then the triple point
D. May increase or decrease; depends on the substance
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The variation of heat of reaction with temperature at constant pressure is given by the __________ law.
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In a turbine, the fluid expands almost
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A refrigerator works on the principle of __________ law of thermodynamics.
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A Carnot cycle consists of the following steps:
A. Two isothermal and two isentropic
B. Two isobaric and two isothermal
C. Two isochoric and two isobaric
D. Two isothermals and two isochoric
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Which of the following liquid metals has the highest thermal conductivity?
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A solute distributes itself between two nonmiscible solvents in contact with each other in such a way that, at a constant temperature, the ratio of its concentrations in two layers is constant, irrespective of its total amount. This is
B. Followed from Margules equation
C. A corollary of Henry's law
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Mollier chart is a __________ plot.
D. Temperature vs. entropy
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For a thermodynamic system containing 'x' chemical species, the maximum number of phases that can co-exist at equilibrium is
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Chemical potential of ith component of a system is given by
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(∂H/∂T)P is the mathematical expression for
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In the equation PVn = constant, if the value of n = y = Cp/Cv, then it represents a reversible __________ process.
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The work done in an adiabatic change in a particular gas depends upon changes in the __________ only.
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In the reaction, represented by, 2SO2 + O2 2SO3; ΔH = - 42 kcal; the forward reaction will be favoured by
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Tea kept in a thermos flask is vigorously shaken. If the tea is considered as a system, then its temperature will
D. First fall and then rise
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If an ideal solution is formed by mixing two pure liquids in any proportion, then the __________ of mixing is zero
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In the ammonia synthesis reaction, N2 + 3H2 2NH3 + 22.4 kcal, the formation of NH3 will be favoured by
D. Both low temperature and high pressure
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Gibbs free energy of mixing at constant pressure and temperature is always
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Which of the following is not a unit of the equilibrium constant Kp? (where, Δx = number of moles of products number of moles of reactants)
A. (atm)Δx, when Δx is negative
B. (atm)Δx, when Δx is positive
C. Dimensionless, when Δx = 0
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The molar excess Gibbs free energy, gE, for a binary liquid mixture at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The corresponding equation for ln y1, where y1 is the activity co-efficient of component 1, is
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The relation connecting the fugacities of various components in a solution with one another and to composition at constant temperature and pressure is called the __________ equation.
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The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv), depends upon its
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Consider the reaction, C + O2 CO2; ΔH = - 94 kcal. What will be the value of ΔH for the reaction CO2 → C + O2?
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Fugacity is a measure of the
A. Escaping tendencies of the same substance in different phases of a system
B. Relative volatility of a mixture of two miscible liquids
C. Behaviour of ideal gases
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Pick out the correct statement.
A. The available energy in an isolated system for all irreversible (real) processes decreases
B. The efficiency of a Carnot engine increases, if the sink temperature is decreased
C. The reversible work for compression in non-flow process under isothermal condition is the change in Helmholtz free energy
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Which of the following processes cannot be made reversible even under ideal condition of operation?
A. Free expansion of a gas
B. Compression of air in a compressor
C. Expansion of steam in a turbine
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Pick out the extensive property out of the following.
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With increase in compression ratio, the efficiency of the otto engine
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The energy of activation of exothermic reaction is
C. Very large compared to that for endothermic reaction
D. Not possible to predict