Related Questions
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What is the ratio of adiabatic compressibility to isothermal compressibility?
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For a single component two phase mixture, the number of independent variable properties are
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Degrees of freedom at triple point will be
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For an ideal solution, the value of activity co-efficient is
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Degree of freedom of a system consisting of a gaseous mixture of H2 and NH3 will be
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The internal energy of an incompressible fluid depends upon its
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High __________ is an undesirable property for a good refrigerant.
B. Latent heat of vaporisation
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Which is not a refrigerant?
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The rate at which a substance reacts is proportional to its active mass and the rate of a chemical reaction is proportional to the product of active masses of the reacting substances. This is the
B. Statement of Van't Hoff Equation
C. Le-Chatelier's principle
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Heat evolved/absorbed during conversion of a substance from one allotropic form to another is termed as the heat of
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The standard state of a gas (at a given temperature) is the state in which fugacity is equal to
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Gibbs-Duhem equation
A. States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
B. Applies only to binary systems
C. Finds no application in gas-liquid equilibria involved in distillation
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The kinetic energy of gas molecule is zero at
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Compressibility factor of a gas is
A. Not a function of its pressure
B. Not a function of its nature
C. Not a function of its temperature
D. Unity, if it follows PV = nRT
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The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and pressure. It is given by
B. (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj
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At constant temperature and pressure, for one mole of a pure substance, the ratio of the free energy to the chemical potential is
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Trouton's ratio of __________ liquids is calculated using Kistyakowsky equation.
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As pressure approaches zero, the ratio of fugacity to pressure (f/P) for a gas approaches
D. An indeterminate value
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The gas law (PV = RT) is true for an __________ change.
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Work done may be calculated by the expression ∫ p dA for __________ processes.
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Cv is given by
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A thermodynamic system is taken from state A to B along ACB and is brought back to A along BDA as shown below in the P-V diagram. The net work done during the complete cycle is given by the area covered by
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Which one is true for a throttling process?
A. A gas may have more than one inversion temperatures
B. The inversion temperature is different for different gases
C. The inversion temperature is same for all gases
D. The inversion temperature is the temperature at which Joule-Thomson co-efficient is infinity
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Pick out the wrong statement.
A. The chemical potential of a pure substance depends upon the temperature and pressure
B. The chemical potential of a component in a system is directly proportional to the escaping tendency of that component
C. The chemical potential of ith species (μi) in an ideal gas mixture approaches zero as the pressure or mole fraction (xi) tends to be zero at constant temperature
D. The chemical potential of species 'i' in the mixture (μi) is mathematically represented as,μi = ∂(nG)/∂ni]T,P,nj where, n, ni and nj respectively denote the total number of moles, moles of ith species and all mole numbers except ith species. 'G' is Gibbs molar free energy
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Joule-Thomson Co-efficient at any point on the inversion curve is
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Entropy of a substance remains constant during a/an __________ change.
B. Irreversible isothermal
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For an irreversible process involving only pressure-volume work
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Lowering of condenser temperature (keeping the evaporator temperature constant) in case of vapour compression refrigeration system results in
D. Increased or decreased COP; depending upon the type of refrigerant
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The first law of thermodynamics is a restatement of the law of conservation of
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With increase in compression ratio, the efficiency of the otto engine