Related Questions
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4
Ideal gas law is applicable at
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Fugacity is a measure of the
A. Escaping tendencies of the same substance in different phases of a system
B. Relative volatility of a mixture of two miscible liquids
C. Behaviour of ideal gases
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4
In case of an __________ process, the temperature of the system increases.
A. Isothermal compression
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The compressibility factor for an ideal gas is 1. Its value for any other real gas is
D. Either (B) or (C), depends on the nature of the gas
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If the vapour pressure at two temperatures of a solid phase in equilibrium with its liquid phase are known, then the latent heat of fusion can be calculated by the
B. Clausius-Clapeyron Equation
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The number of degree of freedom for an Azeotropic mixture of ethanol and water in vapourliquid equilibrium, is
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Which of the following is not an intensive property?
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Specific/molar Gibbs free energy for a pure substance does not change during
D. Either (A), (B) or (C)
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Change of heat content when one mole of compound is burnt in oxygen at constant pressure is called the
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During adiabatic expansion of gas
A. Pressure remains constant
C. Temperature remains constant
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The equation relating E, P, V and T which is true for all substances under all conditions is given by (∂E/∂V)T = T(∂P/∂T)H - P. This equation is called the
B. Thermodynamic equation of state
D. Redlich-Kwong equation of state
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An ideal monatomic gas is taken round the cycle ABCDA as shown below in the P-V diagram. The work done during the cycle is
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Which of the following is not an extensive property?
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In any spontaneous process,
C. Both F and A decreases
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Internal energy of an ideal gas
A. Increases with increase in pressure
B. Decreases with increase in temperature
C. Is independent of temperature
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__________ functions are exemplified by heat and work.
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Those solutions in which there is no volume change upon mixing the components in the liquid state and which, when diluted do not undergo any heat change (i.e. heat of dilution is zero), are called __________ solutions.
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The free energy change for a chemical reaction is given by (where, K = equilibrium constant)
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The thermodynamic law, PVy = constant, is not applicable in case of
A. Ideal compression of air
B. Free expansion of an ideal gas
C. Adiabatic expansion of steam in a turbine
D. Adiabatic compression of a perfect gas
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Free energy change at equilibrium is
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In a P-V diagram (for an ideal gas), an isothermal curve will coincide within adiabatic curve (through a point), when
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Fugacity and pressure are numerically not equal for the gases
A. At low temperature and high pressure
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An isentropic process is carried out at constant
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Pick out the wrong statement.
A. Trouton's ratio of non-polar liquids is calculated using Kistyakowsky equation
B. Thermal efficiency of a Carnot engine is always less than 1
C. An equation relating pressure, volume and temperature of a gas is called ideal gas equation
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A gas shows deviation from ideal behaviour at
A. Low pressure and high temperature
B. Low pressure and low temperature
C. Low temperature and high pressure
D. High temperature and high pressure
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Consider the reaction, C + O2 CO2; ΔH = - 94 kcal. What will be the value of ΔH for the reaction CO2 → C + O2?
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Which of the following is not a common refrigerant?
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Gibbs free energy at constant pressure and temperature under equilibrium conditions is
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The compressibility factor of a gas is given by (where, V1 = actual volume of the gas V2 = gas volume predicted by ideal gas law)
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The expression for entropy change given by, ΔS = nR ln (V2/V1) + nCv ln (T2/T1) is valid for
A. Reversible isothermal volume change
B. Heating of a substance
C. Cooling of a substance
D. Simultaneous heating and expansion of an ideal gas