Related Questions
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The ratio of equilibrium constants (Kp2/Kp1) at two different temperatures is given by
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Change of heat content when one mole of compound is burnt in oxygen at constant pressure is called the
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Change of state namely evaporation condensation, freezing and melting is an __________ process.
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As pressure approaches zero, the ratio of fugacity to pressure (f/P) for a gas approaches
D. An indeterminate value
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In case of a close thermodynamic system, there is __________ across the boundaries.
A. No heat and mass transfer
B. No mass transfer but heat transfer
C. Mass and energy transfer
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A gas can be liquefied by pressure alone only, when its temperature is __________ its critical temperature.
C. Equal to or higher than
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A/an __________ system is exemplified by a vessel containing a volatile liquid in contact with its vapor.
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Free energy changes for two reaction mechanism 'X' and 'Y are respectively - 15 and - 5 units. It implies that X is
C. Three times slower than Y
D. Three times faster than Y
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Dryness fraction of wet steam is defined as the ratio of mass of vapour in the mixture to the mass of mixture __________ calorimeter is not used for measuring the dryness fraction of steam.
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The number of degrees of freedom for an azeotropic mixture in a two component vapour-liquid equilibria is/are
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In case of the decomposition of hydroiodic acid (2HI H2 + I2), addition of H2 (at equilibrium condition) will
A. Increase the partial pressure of I2
B. Decrease the partial pressure of HI
C. Diminish the degree of dissociation of HI
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Equilibrium constant of a reaction varies with the
A. Initial concentration of the reactant
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__________ decreases during adiabatic throttling of a perfect gas.
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If atmospheric temperature and dew point are nearly equal, then the relative humidity is
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A change in state involving a decrease in entropy can be spontaneous, only if
C. It takes place isothermally
D. It takes place at constant volume
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1st law of thermodynamics is nothing but the law of conservation of
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The first law of thermodynamics is a restatement of the law of conservation of
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Air enters an adiabatic compressor at 300K. The exit temperature for a compression ratio of 3, assuming air to be an ideal gas (Y = Cp/Cv = 7/5) and the process to be reversible, is
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The point at which all the three (solid, liquid and gas) phases co-exist, is known as the __________ point.
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While dissolving a gas into a liquid at a constant temperature, the ratio of the concentration of the gas in the solution phase and in the gaseous phase is
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Ideal refrigeration cycle is
B. Same as reverse Carnot cycle
C. Dependent on the refrigerant's properties
D. The least efficient of all refrigeration processes
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One mole of nitrogen at 8 bar and 600 K is contained in a piston-cylinder arrangement. It is brought to 1 bar isothermally against a resisting pressure of 1 bar. The work done (in Joules) by the gas is
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The amount of heat required to decompose a compound into its elements is __________ the heat of formation of that compound from its elements.
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All gases during throttling process at atmospheric temperature and pressure show a cooling effect except
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Pressure-enthalpy chart is useful in refrigeration. The change in internal energy of an ideal fluid used in ideal refrigeration cycle is
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The internal energy of an ideal gas does not change in a reversible __________ process.
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At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is
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A system undergoes a change from a given initial state to a given final state either by an irreversible process or by a reversible process, then (where, Δ S1 and Δ SR are the entropy changes of the system for the irreversible and reversible processes respectively)
B. Δ S1 is sometimes > Δ SR
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With increase in compression ratio, the efficiency of the otto engine
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At __________ point, all the three phases (i.e. solid, liquid and gas) co-exist.