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The efficiency of a Carnot heat engine operating between absolute temperatures T1 and T2 (when, T1 > T2) is given by (T1 - T2)/T1. The co-efficient of performance (C.O.P.) of a Carnot heat pump operating between T1 and T2 is given by
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4
For an incompressible fluid, the __________ is a function of both pressure as well as temperature.
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Entropy change for an irreversible isolated system is
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At 60° C, vapour pressure of methanol and water are 84.562 kPa and 19.953 kPa respectively. An aqueous solution of methanol at 60° C exerts a pressure of 39.223 kPa; the liquid phase and vapour phase mole fractions of methanol are 0.1686 and 0.5714 respectively. Activity co-efficient of methanol is
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Number of phases in a colloidal system is:
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Internal energy of an element at 1 atm and 25° C is __________ kcal/kg.mole.
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Efficiency of a Carnot engine working between temperatures T1 and T2 (T1 < T) is
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Melting of ice is an example of an __________ process.
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All gases during throttling process at atmospheric temperature and pressure show a cooling effect except
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Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature.
D. Decreases logarithmically
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Compressibility factor (i.e., the ratio of actual volume of gas to the volume predicted by ideal gas law) for all gases are
A. Always greater than one
B. Same at the same reduced temperature
C. Same at the same reduced pressure
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Critical solution temperature (or the consolute temperature) for partially miscible liquids (e.g., phenol-water) is the minimum temperature at which
A. A homogeneous solution (say of phenol water) is formed
B. Mutual solubility of the two liquids shows a decreasing trend
C. Two liquids are completely separated into two layers
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Entropy, which is a measure of the disorder of a system, is:
A. Independent of pressure
B. Independent of temperature
C. Zero at absolute zero temperature for a perfect crystalline substance
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Degree of freedom of the system ice-watervapour will be
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In an ideal gas mixture, fugacity of a species is equal to its
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The equation, Cp - Cv = R, is true for __________ gas.
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Pick out the wrong statement.
A. The chemical potential of a pure substance depends upon the temperature and pressure
B. The chemical potential of a component in a system is directly proportional to the escaping tendency of that component
C. The chemical potential of ith species (μi) in an ideal gas mixture approaches zero as the pressure or mole fraction (xi) tends to be zero at constant temperature
D. The chemical potential of species 'i' in the mixture (μi) is mathematically represented as,μi = ∂(nG)/∂ni]T,P,nj where, n, ni and nj respectively denote the total number of moles, moles of ith species and all mole numbers except ith species. 'G' is Gibbs molar free energy
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The number of degrees of freedom for a mixture of ice and water (liquid) are
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A domestic refrigerator has a/an __________ cooled condenser.
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Which of the following is not an equation of state?
B. Clausius-Clapeyron equation
C. Beattie-Bridgeman equation
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Boyle's law for gases states that
A. P ∝ 1/V, when temperature is constant
B. P ∝ 1/V, when temperature & mass of the gas remain constant
C. P ∝ V, at constant temperature & mass of the gas
D. P/V = constant, for any gas
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In vapour compression refrigeration system, if the evaporator temperature and the condenser temperatures are -13°C and 37°C respectively, the Carnot COP will be
D. Data insufficient, can't be found out
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The equilibrium constant for a chemical reaction at two different temperatures is given by
A. Kp2/Kp1 = - (ΔH/R) (1/T2 - 1/T1)
B. Kp2/Kp1 = (ΔH/R) (1/T2 - 1/T1)
C. Kp2/Kp1 = ΔH (1/T2 - 1/T1)
D. Kp2/Kp1 = - (1/R) (1/T2 - 1/T1)
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dW and dq are not the exact differential, because q and W are
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A solid is transformed into vapour without going to the liquid phase at
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If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as
A. Solubility increases as temperature increases
B. Solubility increases as temperature decreases
C. Solubility is independent of temperature
D. Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution
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Heat pump
A. Accomplishes only space heating in winter
B. Accomplishes only space cooling in summer
C. Accomplishes both (A) and (B)
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Heat evolved/absorbed during conversion of a substance from one allotropic form to another is termed as the heat of
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Cv is given by
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In the reaction, C + O2 → CO2; ΔH = - 94 kcal. What is the heat content (enthalpy) of O2?