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4

The absolute entropy for all crystalline substances at absolute zero temperature is

A. Zero

B. Negative

C. More than zero

D. Indeterminate

Correct Answer :

A. Zero


Related Questions

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4

The internal energy of an ideal gas is a function of its __________ only.

A. Molecular size

B. Volume

C. Pressure

D. Temperature

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4

The gas law (PV = RT) is true for an __________ change.

A. Isothermal

B. Adiabatic

C. Both (A) & (B)

D. Neither (A) nor (B)

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4

Enthalpy of a gas depends upon its

A. Temperature

B. Mass

C. Volume

D. Pressure

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4

At normal boiling point, molar entropy of vaporisation is __________ Joule/K°.mole.

A. 72

B. 92

C. 142

D. 192

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4

In the equation, PVn = constant, if the value of n is in between 1 and y (i.e. Cp/Cv), then it represents a reversible __________ process.

A. Isometric

B. Polytropic

C. Isentropic

D. Isobaric

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4

Critical temperature is defined as the temperature above which a gas will

A. Not liquify (barring exceptions)

B. Immediately liquify

C. Never liquify however high the pressure may be

D. None of these

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4

Pick out the wrong statement.

A. At constant pressure, solubility of a gas in a liquid diminishes with rise in temperature

B. Normally, the gases which are easily liquefied are more soluble in common solvents

C. The gases which are capable of forming ions in aqueous solution are much more soluble in water than in other solvents

D. At constant pressure, solubility of a gas in a liquid increases with rise in temperature

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4

A solute distributes itself between two nonmiscible solvents in contact with each other in such a way that, at a constant temperature, the ratio of its concentrations in two layers is constant, irrespective of its total amount. This is

A. The distribution law

B. Followed from Margules equation

C. A corollary of Henry's law

D. None of these

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4

The temperature at which a real gas obeys the ideal gas laws over a wide range of pressure is called __________ temperature.

A. Boyle

B. Inversion

C. Critical

D. Reduced

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4

Which one is true for a throttling process?

A. A gas may have more than one inversion temperatures

B. The inversion temperature is different for different gases

C. The inversion temperature is same for all gases

D. The inversion temperature is the temperature at which Joule-Thomson co-efficient is infinity

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4

Charles' law for gases states that

A. V/T = Constant

B. V ∝ 1/T

C. V ∝ 1/P

D. PV/T = Constant

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4

Pick out the wrong statement.

A. The net change in entropy in any reversible cycle is always zero

B. The entropy of the system as a whole in an irreversible process increases

C. The entropy of the universe tends to a maximum

D. The entropy of a substance does not remain constant during a reversible adiabatic change

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4

Absorption/evolution of heat during conversion of a substance from one allotropic form to another is termed as the heat of

A. Sublimation

B. Fusion

C. Transition

D. Vaporisation

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4

1st law of thermodynamics is nothing but the law of conservation of

A. Momentum

B. Mass

C. Energy

D. None of these

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4

Which of the following processes cannot be made reversible even under ideal condition of operation?

A. Free expansion of a gas

B. Compression of air in a compressor

C. Expansion of steam in a turbine

D. All (A), (B) & (C)

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4

A domestic refrigerator has a/an __________ cooled condenser.

A. Water

B. Air

C. Evaporative

D. Gas

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4

Pick out the wrong statement.

A. The values of (∂P/∂V)T and (∂2P/∂V2)T are zero for a real gas at its critical point

B. Heat transferred is equal to the change in the enthalpy of the system, for a constant pressure, non-flow, mechanically reversible process

C. Thermal efficiency of a Carnot engine depends upon the properties of the working fluid besides the source & sink temperatures

D. During a reversible adiabatic process, the entropy of a substance remains constant

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4

For the reversible exothermic reaction, N2 + 3H2 2NH3, increase of pressure would

A. Shift the equilibrium towards right

B. Give higher yield of NH3

C. Both (B) and (C)

D. Neither (A) nor (B)

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4

Fugacity is most helpful in

A. Representing actual behaviour of real gases

B. Representing actual behaviour of ideal gases

C. The study of chemical equilibria involving gases at atmospheric pressure

D. None of these

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4

__________ law of thermodynamics ascertains the direction of a particular spontaneous process.

A. Zeroth

B. First

C. Second

D. Third

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4

Partial molar free energy of an element A in solution is same as its

A. Chemical potential

B. Activity

C. Fugacity

D. Activity co-efficient

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4

Internal energy is equal to the heat absorbed in case of a/an __________ process.

A. Constant volume

B. Polytropic

C. Adiabatic

D. Constant pressure

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4

The variation of heat of reaction with temperature at constant pressure is given by the __________ law.

A. Kelvin's

B. Antoines

C. Kirchoffs

D. None of these

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4

The third law of thermodynamics states that the

A. Heat capacity of a crystalline solid is zero at absolute zero temperature

B. Heat transfer from low temperature to high temperature source is not possible without external work

C. Gases having same reduced properties behaves similarly

D. None of these

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4

Compound having large heat of formation is

A. More stable

B. Less stable

C. Not at all stable (like nascent O2)

D. Either more or less stable; depends on the compound

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4

Gibbs free energy (F) is defined as

A. F = E - TS

B. F = H - TS

C. F = H + TS

D. F = E + TS

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4

What happens in a reversible adiabatic expansion process?

A. Heating takes place

B. Cooling takes place

C. Pressure is constant

D. Temperature is constant

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4

Solid and liquid phases of a substance are in equilibrium at the

A. Critical temperature

B. Melting point

C. Freezing point

D. Both (B) and (C)

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4

Adiabatic compression of a saturated water vapour makes it

A. Supersaturated

B. Superheated

C. Both (A) and (B)

D. Neither (A) nor (B)

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4

The temperature at the eutectic point of the system is the __________ temperature that can be attained in the system.

A. Lowest

B. Highest

C. Average

D. None of these