Temperature
Pressure
Composition
All (A), (B) and (C)
D. All (A), (B) and (C)
5 & 3
3.987 & 1.987
1.987 & 0.66
0.66 & 1.987
Is the most efficient of all refrigeration cycles
Has very low efficiency
Requires relatively large quantities of air to achieve a significant amount of refrigeration
Both (B) and (C)
Temperature
Pressure
Volume
Entropy
0
1
2
3
Minimum
Zero
Maximum
Indeterminate
The values of (∂P/∂V)T and (∂2P/∂V2)T are zero for a real gas at its critical point
Heat transferred is equal to the change in the enthalpy of the system, for a constant pressure, non-flow, mechanically reversible process
Thermal efficiency of a Carnot engine depends upon the properties of the working fluid besides the source & sink temperatures
During a reversible adiabatic process, the entropy of a substance remains constant
∞
-ve
0
+ve
(∂E/∂ni)S, v, nj
(∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj
(∂H/∂ni)S, P, nj
All (A), (B) and (C)
Closed
Open
Isolated
Non-thermodynamic
-273
0
-78
5
Polar
Non-polar
Both (A) & (B)
Neither (A) nor (B)
Free energy
Entropy
Refractive index
None of these
Decrease on addition of Cl2
Increase on addition of an inert gas at constant pressure
Decrease on increasing the pressure of the system
None of these
Kelvin's
Antoines
Kirchoffs
None of these
dQ = dE + dW
dQ = dE - dW
dE = dQ + dW
dW = dQ + dE
μi = (∂F/∂ni)T, P, ni
μi = (∂A/∂ni)T, P, ni
μi = (∂F/∂ni)T, P
μi = (∂A/∂ni)T, P
Molecular size
Volume
Pressure
Temperature
Zeroth
First
Second
Third
λb/Tb
Tb/λb
√(λb/Tb)
√(Tb/λb)
States that n1dμ1 + n2dμ2 + ....njdμj = 0, for a system of definite composition at constant temperature and pressure
Applies only to binary systems
Finds no application in gas-liquid equilibria involved in distillation
None of these
Enhanced COP
Decreased COP
No change in the value of COP
Increased or decreased COP; depending upon the type of refrigerant
∞
0
Maximum
Minimum
SO2
NH3
CCl2F2
C2H4Cl2
Volume of the liquid phase is negligible compared to that of vapour phase
Vapour phase behaves as an ideal gas
Heat of vaporisation is independent of temperature
All (A), (B) & (C)
Same
Doubled
Halved
One fourth of its original value
Increase
Decrease
No change
None of these
Minimum number of degree of freedom of a system is zero
Degree of freedom of a system containing a gaseous mixture of helium, carbon dioxide and hydrogen is 4
For a two phase system in equilibrium made up of four non-reacting chemical species, the number of degrees of freedom is 4
Enthalpy and internal energy change is zero during phase change processes like melting, vaporisation and sublimation
ds = 0
ds < 0
ds > 0
ds = Constant
0
1
2
3
ΔF = ΔH + T [∂(ΔF)/∂T]P
ΔF = ΔH - TΔT
d(E - TS) T, V < 0
dP/dT = ΔHvap/T.ΔVvap