Less pronounced
More pronounced
Equal
Data insufficient, can't be predicted
B. More pronounced
Increases
Decreases
Remains unchanged
Data insufficient, can't be predicted
Tds = dE + dW
dE - dW = Tds
dW - dE = Tds
Tds - dW + dE >0
1st
Zeroth
3rd
None of these
Cp of monatomic gases such as metallic vapor is about 5 kcal/kg.atom
The heat capacity of solid inorganic substance is exactly equal to the heat capacity of the substance in the molten state
There is an increase in entropy, when a spontaneous change occurs in an isolated system
At absolute zero temperature, the heat capacity for many pure crystalline substances is zero
Pressure
Composition
Temperature
All (A), (B) and (C)
R loge 4
R log10 4
Cv log10 4
Cv loge 4
Entropy
Temperature
Enthalpy
Pressure
Direction of energy transfer
Reversible processes only
Irreversible processes only
None of these
Gibbs-Duhem
Maxwell's
Clapeyron
None of these
TVγ-1 = constant
p1-γ.TY = constant
PVγ = constant
None of these
Amount of energy transferred
Direction of energy transfer
Irreversible processes only
Non-cyclic processes only
1
2
3
4
Violates second law of thermodynamics
Involves transfer of heat from low temperature to high temperature
Both (A) and (B)
Neither (A) nor (B)
V1/V2
V2/V1
V1 - V2
V1.V2
Chemical potential
Fugacity
Both (A) and (B)
Neither (A) nor (B)
Adiabatic process
Endothermic reaction
Exothermic reaction
Process involving a chemical reaction
(∂E/∂ni)S, v, nj
(∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj
(∂H/∂ni)S, P, nj
All (A), (B) and (C)
The energy change of a system undergoing any reversible process is zero
It is not possible to transfer heat from a lower temperature to a higher temperature
The total energy of system and surrounding remains the same
None of the above
Rectangle
Rhombus
Trapezoid
Circle
Zero
Negative
Very large compared to that for endothermic reaction
Not possible to predict
Pressure to critical pressure
Critical pressure to pressure
Pressure to pseudocritical pressure
Pseudocritical pressure to pressure
T
√T
T2
1/√T
Prediction of the extent of a chemical reaction
Calculating absolute entropies of substances at different temperature
Evaluating entropy changes of chemical reaction
Both (B) and (C)
More stable
Less stable
Not at all stable (like nascent O2)
Either more or less stable; depends on the compound
CV
Enthalpy change
Free energy change
None of these
Escaping tendencies of the same substance in different phases of a system
Relative volatility of a mixture of two miscible liquids
Behaviour of ideal gases
None of these
1
2
3
0
Oxygen
Nitrogen
Air
Hydrogen
(dF)T, p <0
(dF)T, p = 0
(dF)T, p > 0
(dA)T, v >0
Volume
Pressure
Temperature
All a, b & c