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4

The free energy change for a chemical reaction is given by (where, K = equilibrium constant)

A. RT ln K

B. -RT ln K

C. -R ln K

D. T ln K

Correct Answer :

B. -RT ln K


Related Questions

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4

Melting of ice is an example of an __________ process.

A. Adiabatic

B. Isothermal

C. Isometric

D. None of these

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4

Joule-Thomson co-efficient which is defined as, η = (∂T/∂P)H = 1/Cp (∂H/∂T)P, changes sign at a temperature known as inversion temperature. The value of Joule-Thomson co-efficient at inversion temperature is

A. 0

B.

C. +ve

D. -ve

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4

For the reversible exothermic reaction, N2 + 3H2 2NH3, increase of pressure would

A. Shift the equilibrium towards right

B. Give higher yield of NH3

C. Both (B) and (C)

D. Neither (A) nor (B)

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4

Change of heat content when one mole of compound is burnt in oxygen at constant pressure is called the

A. Calorific value

B. Heat of reaction

C. Heat of combustion

D. Heat of formation

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4

Gibbs free energy (G) is represented by, G = H - TS, whereas Helmholtz free energy, (A) is given by, A = E - TS. Which of the following is the Gibbs-Helmholtz equation?

A. [∂(G/T)/∂T] = - (H/T2)

B. [∂(A/T)/∂T]V = - E/T2

C. Both (A) and (B)

D. Neither (A) nor (B)

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4

Free energy change of mixing two liquid substances is a function of the

A. Concentration of the constituents only

B. Quantities of the constituents only

C. Temperature only

D. All (A), (B) and (C)

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4

Gibbs-Duhem equation relates composition in liquid phase and the __________ at constant temperature & pressure.

A. Fugacity

B. Partial pressure

C. Activity co-efficient

D. All (A), (B), and (C)

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4

In a reversible process

A. Tds = dE + dW

B. dE - dW = Tds

C. dW - dE = Tds

D. Tds - dW + dE >0

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4

The first law of thermodynamics is a restatement of the law of conservation of

A. Mass

B. Energy

C. Momentum

D. None of these

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4

Charles' law for gases states that

A. V/T = Constant

B. V ∝ 1/T

C. V ∝ 1/P

D. PV/T = Constant

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4

At absolute zero temperature, the __________ of the gas is zero.

A. Pressure

B. Volume

C. Mass

D. None of these

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4

The equation, PV = nRT, is best obeyed by gases at

A. Low pressure & high temperature

B. High pressure & low temperature

C. Low pressure & low temperature

D. None of these

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4

One mole of nitrogen at 8 bar and 600 K is contained in a piston-cylinder arrangement. It is brought to 1 bar isothermally against a resisting pressure of 1 bar. The work done (in Joules) by the gas is

A. 30554

B. 10373

C. 4988.4

D. 4364.9

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4

With increase in pressure (above atmospheric pressure), the Cp of a gas

A. Increases

B. Decreases

C. Remains unchanged

D. First decreases and then increases

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4

Tea kept in a thermos flask is vigorously shaken. If the tea is considered as a system, then its temperature will

A. Increase

B. Decrease

C. Remain unchanged

D. First fall and then rise

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4

In case of the decomposition of hydroiodic acid (2HI H2 + I2), addition of H2 (at equilibrium condition) will

A. Increase the partial pressure of I2

B. Decrease the partial pressure of HI

C. Diminish the degree of dissociation of HI

D. None of these

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4

The extensive properties are

A. Volume, mass and number of moles

B. Free energy, entropy and enthalpy

C. Both (A) and (B)

D. None of these

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4

Heat of reaction at constant volume is identified with __________ change.

A. Enthalpy

B. Internal energy

C. Either (A) or (B)

D. Neither (A) nor (B)

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4

The standard Gibbs free energy change of a reaction depends on the equilibrium

A. Pressure

B. Temperature

C. Composition

D. All (A), (B) and (C)

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4

If the pressure on 100 c.c. of air is halved, then its volume (at the same temperature) would be __________ c.c.

A. 100

B. 50

C. 205

D. 200

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4

Ideal refrigeration cycle is

A. Same as Carnot cycle

B. Same as reverse Carnot cycle

C. Dependent on the refrigerant's properties

D. The least efficient of all refrigeration processes

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4

Which of the following is true for Virial equation of state?

A. Virial co-efficients are universal constants

B. Virial co-efficients 'B' represents three body interactions

C. Virial co-efficients are function of temperature only

D. For some gases, Virial equations and ideal gas equations are the same

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4

If atmospheric temperature and dew point are nearly equal, then the relative humidity is

A. Zero

B. 50%

C. Almost 100%

D. unpredictable

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4

Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the __________ equation.

A. Gibbs-Duhem

B. Maxwell's

C. Clapeyron

D. None of these

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4

Generation of heat by friction is an example of a/an __________ change.

A. Isothermal

B. Irreversible

C. Adiabatic

D. Reversible

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4

The amount of heat required to decompose a compound into its elements is __________ the heat of formation of that compound from its elements.

A. Less than

B. More than

C. Same as

D. Not related to

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4

Claude gas liquefaction process employs cooling

A. At constant pressure

B. By throttling

C. By expansion in an engine

D. None of these

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4

An ideal monatomic gas is taken round the cycle ABCDA as shown below in the P-V diagram. The work done during the cycle is

A. PV

B. 2PV

C. PV/2

D. 0

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4

A domestic refrigerator has a/an __________ cooled condenser.

A. Water

B. Air

C. Evaporative

D. Gas

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4

Standard temperature and pressure (S.T.P.) is

A. 0°C and 750 mm Hg

B. 15°C and 750 mm Hg

C. 0°C and 1 kgf/cm2

D. 15°C and 1 kgf/cm2