Boyle
Inversion
Critical
Reduced
A. Boyle
Solid-vapor
Solid-liquid
Liquid-vapor
All (A), (B) and (C)
0
1
2
3
Internal energy
Enthalpy
Entropy
All (A), (B) & (C)
1
< 1
> 1
>> 1
Specific heat
Latent heat of vaporisation
Viscosity
Specific vapor volume
Melting of ice
Condensation of alcohol vapor
Sudden bursting of a cycle tube
Evaporation of water
Isochoric
Isobaric
Adiabatic
Isothermal
Expansion of a real gas
Reversible isothermal volume change
Heating of an ideal gas
Cooling of a real gas
+ve
0
-ve
∞
0
1
2
3
Like internal energy and enthalpy, the absolute value of standard entropy for elementary substances is zero
Melting of ice involves increase in enthalpy and a decrease in randomness
The internal energy of an ideal gas depends only on its pressure
Maximum work is done under reversible conditions
Low pressure & high temperature
High pressure & low temperature
Low pressure & low temperature
None of these
Critical
Boyle
Inversion
Reduced
Moisture free ice
Solid helium
Solid carbon dioxide
None of these
Gibbs-Duhem
Van Laar
Gibbs-Helmholtz
Margules
Increase
Decrease
Not alter
None of these
Is zero
Increases
Decreases whereas the entropy increases
And entropy both decrease
Increases with increase in pressure
Decreases with increase in temperature
Is independent of temperature
None of these
Turbine
Heat engine
Reversed heat engine
None of these
RT d ln P
R d ln P
R d ln f
None of these
Hess's
Kirchoff's
Lavoisier and Laplace
None of these
Oxygen
Nitrogen
Air
Hydrogen
(∂P/∂V)T
(∂V/∂T)P
(∂P/∂V)V
All (A), (B) & (C)
Volume of the liquid phase is negligible compared to that of vapour phase
Vapour phase behaves as an ideal gas
Heat of vaporisation is independent of temperature
All (A), (B) & (C)
F = A + PV
F = E + A
F = A - TS
F = A + TS
RT ln K
-RT ln K
-R ln K
T ln K
Simultaneous pressure & temperature change
Heating
Cooling
Both (B) and (C)
Helmholtz
Gibbs
Both a & b
Neither 'a' nor 'b'
A refrigeration cycle violates the second law of thermodynamics
Refrigeration cycle is normally represented by a temperature vs. entropy plot
In a refrigerator, work required decreases as the temperature of the refrigerator and the temperature at which heat is rejected increases
One ton of refrigeration is equivalent to the rate of heat absorption equal to 3.53 kW
Molal concentration difference
Molar free energy
Partial molar free energy
Molar free energy change