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The variation of heat of reaction with temperature at constant pressure is given by the __________ law.

A. Kelvin's

B. Antoines

C. Kirchoffs

D. None of these

Correct Answer :

C. Kirchoffs


Related Questions

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The unit of fugacity is the same as that of the

A. Pressure

B. Temperature

C. Volume

D. Molar concentration

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4

The intensive properties are

A. Molar volume, density, viscosity and boiling point

B. Refractive index and surface tension

C. Both (A) and (B)

D. None of these

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4

One ton of refrigeration is defined as the heat rate corresponding to melting of one ton of ice in one

A. Hour

B. Day

C. Minute

D. Second

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4

Gibbs-Duhem equation

A. States that n11 + n22 + ....njj = 0, for a system of definite composition at constant temperature and pressure

B. Applies only to binary systems

C. Finds no application in gas-liquid equilibria involved in distillation

D. None of these

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The compressibility factor for an ideal gas is 1. Its value for any other real gas is

A. 1

B. < 1

C. > 1

D. Either (B) or (C), depends on the nature of the gas

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4

The point at which all the three (solid, liquid and gas) phases co-exist, is known as the __________ point.

A. Freezing

B. Triple

C. Boiling

D. Boyle

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4

Heat of formation of an element in its standard state is

A. 0

B. < 0

C. > 0

D. A function of pressure

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During a reversible isothermal expansion of an ideal gas, the entropy change is

A. +ve

B. 0

C. -ve

D.

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Reduced pressure of a gas is the ratio of its

A. Pressure to critical pressure

B. Critical pressure to pressure

C. Pressure to pseudocritical pressure

D. Pseudocritical pressure to pressure

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4

Standard temperature and pressure (S.T.P.) is

A. 0°C and 750 mm Hg

B. 15°C and 750 mm Hg

C. 0°C and 1 kgf/cm2

D. 15°C and 1 kgf/cm2

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The reaction A (l) → R(g) is allowed to reach equilibrium conditions in an autoclave. At equilibrium, there are two phases, one a pure liquid phase of A and the other a vapor phase of A, R and S. Initially A alone is present. The numbers of degrees of freedom are:

A. 1

B. 2

C. 3

D. 0

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Van Laar equation deals with the activity coefficients in

A. Binary solutions

B. Ternary solutions

C. Azeotropic mixture only

D. None of these

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Gibbs free energy (G) is represented by, G = H - TS, whereas Helmholtz free energy, (A) is given by, A = E - TS. Which of the following is the Gibbs-Helmholtz equation?

A. [∂(G/T)/∂T] = - (H/T2)

B. [∂(A/T)/∂T]V = - E/T2

C. Both (A) and (B)

D. Neither (A) nor (B)

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In a reversible chemical reaction (where, Δx = number of moles of products-number of moles of reactants)

A. Addition of inert gas favours the forward reaction, when Δx is positive

B. Pressure has no effect on equilibrium, when Δn = 0

C. Addition of inert gas has no effect on the equilibrium constant at constant volume for any value of Δx (+ ve, - ve) or zero)

D. All 'a', 'b' & 'c'

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4

Pick out the wrong statement

A. Phase rule variables are intensive properties

B. Heat and work are both state function

C. The work done by expansion of a gas in vacuum is zero

D. CP and CV are state function

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Joule-Thomson effect i.e., a throttling process is a constant __________ process.

A. Entropy

B. Temperature

C. Internal energy

D. Enthalpy

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Entropy change in case of reversible adiabatic process is

A. Minimum

B. Zero

C. Maximum

D. Indeterminate

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PVγ = Constant (where, γ = Cp/Cv) is valid for a/an __________ process.

A. Isothermal

B. Isentropic

C. Isobaric

D. Adiabatic

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Specific volume of an ideal gas is

A. Equal to its density

B. The reciprocal of its density

C. Proportional to pressure

D. None of these

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The thermodynamic law, PVy = constant, is not applicable in case of

A. Ideal compression of air

B. Free expansion of an ideal gas

C. Adiabatic expansion of steam in a turbine

D. Adiabatic compression of a perfect gas

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Any substance above its critical temperature exists as

A. Saturated vapour

B. Solid

C. Gas

D. Liquid

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In the reaction; N2 + O2 2NO, increasing the pressure will result in

A. Shifting the equilibrium towards right

B. Shifting the equilibrium towards left

C. No change in equilibrium condition

D. None of these

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The difference between isothermal compressibility and adiabatic compressibility for an ideal gas is

A. 0

B. +ve

C. -ve

D.

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4

As the temperature is lowered towards the absolute zero, the value of the quantity (∂ΔF/∂T) approaches

A. Zero

B. Unity

C. Infinity

D. None of these

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Specific __________ does not change during a phase change (e.g. sublimation, melting, vaporisation etc.).

A. Entropy

B. Internal energy

C. Enthalpy

D. Gibbs free energy

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The chemical potential of a component (μi) of a phase is the amount by which its capacity for doing all work, barring work of expansion is increased per unit amount of substance added for an infinitesimal addition at constant temperature and pressure. It is given by

A. (∂E/∂ni)S, v, nj

B. (∂G/∂ni)T, P, nj = (∂A/∂ni) T, v, nj

C. (∂H/∂ni)S, P, nj

D. All (A), (B) and (C)

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For a constant volume process

A. dE = CpdT

B. dE = CvdT

C. dQ = dE + pdV

D. dW = pdV

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Entropy change for an irreversible process taking system and surrounding together is

A. 0

B. > 0

C. < 0

D. None of these

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4

Pick out the wrong statement.

A. A refrigeration cycle violates the second law of thermodynamics

B. Refrigeration cycle is normally represented by a temperature vs. entropy plot

C. In a refrigerator, work required decreases as the temperature of the refrigerator and the temperature at which heat is rejected increases

D. One ton of refrigeration is equivalent to the rate of heat absorption equal to 3.53 kW

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Pick out the correct statement.

A. Entropy and enthalpy are path functions

B. In a closed system, the energy can be exchanged with the surrounding, while matter cannot be exchanged

C. All the natural processes are reversible in nature

D. Work is a state function