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Normal boiling points values are for , - 34C, bromine 58°C, carbon tetrachloride 77°C and oxygen - 183°C. Which of these liquids has the highest vapour pressure at room temperature?
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4
In the process of sublimation, the substance transforms directly
A. from the solid state to the liquid state
B. from the liquid state to gaseous state
C. from the solid state to gaseous state
D. from the liquid state to solid state
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4
Which of the following is an amorphous solid?
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The number of tetrahedral and octahedral voids per atom in a crystal lattice are, respectively
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Which one of the following contains same number of molecules as 4.4 gm of carbon dioxide (mol. wt. of = 44, Mol, wt. of = 64)?
A. 64 gm of sulphur dioxide
B. 4.4 gm of sulphur dioxide
C. 6.4 gm of sulphur dioxide
D. 3.2 gm of sulphur dioxide
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4
Arrange the following in order of increasing inter-molecular forces and boiling points:,He,
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The pressure of the ideal gas is less than the real gas because of the
A. increase in the number of collisions
B. volume occupied by the molecules
C. inter-molecular attraction
D. finite size of molecules
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If all the octahedral sites in a cubic close packed arrangement () are completelyfilled with cations, the empirical formula of the compound could then be
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At a given temperature and pressure 2 volumes of A combine with 5 volumes of B to form 2 volumes of C, and 1 volume of A combines with one volume of B to form 2 volumes of D. Then the formula of C is
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A vessel containing 10 litre of air at atmospheric pressure is connected to an evacuated 9 litre vessel The resulting pressure will be
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The limiting radii ratio for the tetrahedral geometry is
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The molecular velocity of any gas is
A. proportional to absolute temperature
B. proportional to the square root of absolute temperature
C. independent of temperature
D. proportional to die square of absolute temperature
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Which of the following phrases would be incorrect to use?
C. A molecule of a compound
D. A molecule of an element
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Boltzmann constant is given by
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In what ratio by mass carbon monoxide and nitrogen should be mixed so that partial pressure exerted by each gas is same?
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The vapour density of gas A is four times that of gas B. If the molecular weight of gas B is M, then the molecular weight of gas A is
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An element has atomic weight 24 and equivalent weight 11.9. Its valency is
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The ionic radii of and ions are 1.47 and 1.95 , respectively. The most probable type of geometry exhibited by RbBr on the radius ratio rule is
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Three dimensional array of points in space is called
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In anti-fluorite structure the negative ions
A. occupy tetrahedral voids
B. occupy octahedral voids
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The radii of and are 95 pm and 181 pm respectively. Coordination number of is expected to be
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Which of the following contains the same number of atoms as 12 gms: of Magnesium (Atomic weights : Mg = 24, C = 12, Ca = 40)
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The kinetic theory of gases predicts that total kinetic energy of a gaseous assembly depends upon the
B. temperature of the gas
D. pressure, temperature and volume of the gas
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The relation between molecular wt. and vapour density is
A. Molecular wt. = V.D.
B. Molecular wt. = V.D.
D. Molecualr wt = 2 x V.D.
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Lattice energy of a solid is high if
A. the radii of the ions are large
B. radii of the ions are small
C. charge on the ions are small
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Molecular formula of D in the above case is
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The vol. of 20 gm. of hydrogen at N.T.P. is
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In a unit cell of cesium chloride the arrangement of cesium ions is
B. hexagonal close packed
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Number of molecules of carbon dioxide present in 44 gm is
A. 12 x approximately
B. 3 x approximately
C. 6 x approximately
D. 3 x approximately
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The number of molecules is 4.25 g of ammonia are approximately