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4

Which of the following equations is used for the prediction of activity co-efficient from experiments?

A. Van Laar equation

B. Margules equation

C. Wilson's equation

D. All (A), (B) and (C)

Correct Answer :

D. All (A), (B) and (C)


Related Questions

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4

The unity of Planck's constant 'h' in the equation, E = hv is

A. J/s

B. J.S

C. J/kmol

D. kmol/J

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4

Throttling (Joule-Thomson effect) process is a constant __________ process.

A. Enthalpy

B. Entropy

C. Pressure

D. None of these

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4

If atmospheric temperature and dew point are nearly equal, then the relative humidity is

A. Zero

B. 50%

C. Almost 100%

D. unpredictable

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4

For a constant volume process __________ by the system is used only to increase the internal energy.

A. Heat absorbed

B. Work done

C. Both (A) & (B)

D. Neither (A) nor (B)

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4

Claude gas liquefaction process employs cooling

A. At constant pressure

B. By throttling

C. By expansion in an engine

D. None of these

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4

In an irreversible process

A. Tds = dE - dW = 0

B. dE - dW - Tds = 0

C. Tds - dE + dW < 0

D. Tds - dT + dW < 0

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4

dW and dq are not the exact differential, because q and W are

A. State functions

B. Path functions

C. Intensive properties

D. Extensive properties

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4

Which of the following decreases with increase in pressure?

A. Melting point of ice

B. Melting point of wax

C. Boiling point of liquids

D. None of these

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4

In case of the decomposition of hydroiodic acid (2HI H2 + I2), addition of H2 (at equilibrium condition) will

A. Increase the partial pressure of I2

B. Decrease the partial pressure of HI

C. Diminish the degree of dissociation of HI

D. None of these

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4

If the heat of solution of an ideal gas in a liquid is negative, then its solubility at a given partial pressure varies with the temperature as

A. Solubility increases as temperature increases

B. Solubility increases as temperature decreases

C. Solubility is independent of temperature

D. Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution

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4

Which of the following is not an equation of state?

A. Bertholet equation

B. Clausius-Clapeyron equation

C. Beattie-Bridgeman equation

D. None of these

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4

For organic compounds, group contribution method can be used for the estimation of

A. Critical properties

B. Specific gravity

C. Specific volume

D. Thermal conductivity

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If an ideal solution is formed by mixing two pure liquids in any proportion, then the __________ of mixing is zero

A. Enthalpy

B. Volume

C. Both 'a' & 'b'

D. Neither 'a' nor 'b'

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4

A cyclic engine exchanges heat with two reservoirs maintained at 100 and 300°C respectively. The maximum work (in J) that can be obtained from 1000 J of heat extracted from the hot reservoir is

A. 349

B. 651

C. 667

D. 1000

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4

High __________ is an undesirable property for a good refrigerant.

A. Specific heat

B. Latent heat of vaporisation

C. Viscosity

D. Specific vapor volume

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Fundamental principle of refrigeration is based on the __________ law of thermodynamics.

A. Zeroth

B. First

C. Second

D. Third

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Which of the following is an undesirable characteristic of a refrigerant?

A. It should be non-explosive

B. It should have a sub-atmospheric vapor pressure at the temperature in refrigerator coils

C. Its vapor pressure at the condenser temperature should be very high

D. None of these

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4

For a real gas, the chemical potential is given by

A. RT d ln P

B. RT d ln f

C. R d ln f

D. None of these

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4

Pick out the wrong statement

A. Phase rule variables are intensive properties

B. Heat and work are both state function

C. The work done by expansion of a gas in vacuum is zero

D. CP and CV are state function

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4

The energy of activation of exothermic reaction is

A. Zero

B. Negative

C. Very large compared to that for endothermic reaction

D. Not possible to predict

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4

Filling of gas from a high pressure cylinder into small bottles is an example of a/an __________ process.

A. Equilibrium

B. Adiabatic

C. Steady

D. Unsteady

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The chemical potential for a pure substance is __________ its partial molal free energy.

A. More than

B. Less than

C. Equal to

D. Not related to

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4

A closed system is cooled reversibly from 100°C to 50°C. If no work is done on the system

A. its internal energy (U) decreases and its entropy (S) increases

B. U and S both decreases

C. U decreases but S is constant

D. U is constant but S decreases

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A system is said to be isopiestic, if there is no __________ change.

A. Temperature

B. Pressure

C. Volume

D. None of these

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Ideal refrigeration cycle is

A. Same as Carnot cycle

B. Same as reverse Carnot cycle

C. Dependent on the refrigerant's properties

D. The least efficient of all refrigeration processes

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The value of Joule-Thomson co-efficient, in case where cooling occurs after the throttling process is

A. 0

B.

C. +ve

D. -ve

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For equilibrium process (i.e. reversible) in an isolated system

A. ds = 0

B. ds < 0

C. ds > 0

D. ds = Constant

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4

Co-efficient of Performance (COP) of a refrigerator is the ratio of the

A. Work required to refrigeration obtained

B. Refrigeration obtained to the work required

C. Lower to higher temperature

D. Higher to lower temperature

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4

Domestic refrigerator usually works on the __________ refrigeration cycle.

A. Carnot

B. Air

C. Absorption

D. vapour-ejection

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For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system __________ as its mole fraction increases.

A. Decreases

B. Increases

C. Remain same

D. Decreases linearly