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Which of the following is affected by the temperature?

A. Fugacity

B. Activity co-efficient

C. Free energy

D. All (A), (B) & (C)

Correct Answer :

D. All (A), (B) & (C)


Related Questions

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When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change. This is called the

A. Le-Chatelier principle

B. Kopp's rule

C. Law of corresponding state

D. Arrhenius hypothesis

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In Joule-Thomson porous plug experiment, the

A. Enthalpy does not remain constant

B. Entire apparatus is exposed to surroundings

C. Temperature remains constant

D. None of these

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Helmholtz free energy (A) is defined as

A. A = H - TS

B. A = E - TS

C. A = H + TS

D. None of these

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A Carnot cycle consists of the following steps:

A. Two isothermal and two isentropic

B. Two isobaric and two isothermal

C. Two isochoric and two isobaric

D. Two isothermals and two isochoric

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When a system is in equilibrium for all possible processes, the differential or finite change of entropy is

A. < 0

B. > 0

C. = 0

D. None of these

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For a reversible process involving only pressure-volume work

A. (dF)T, p < 0

B. (dF)T, p > 0

C. (dF)T, p = 0

D. (dA)T, v < 0

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Which of the following is not an intensive property?

A. Volume

B. Density

C. Temperature

D. Pressure

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Forward reaction will be favoured for the exothermic reaction, represented by CO + H2O CO2 + H2, by

A. Low temperature and high pressure

B. Low temperature and low pressure

C. High temperature and high pressure

D. High temperature and low pressure

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Joule-Thomson effect i.e., a throttling process is a constant __________ process.

A. Entropy

B. Temperature

C. Internal energy

D. Enthalpy

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Free energy change at equilibrium is

A. Zero

B. Positive

C. Negative

D. Indeterminate

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Work done may be calculated by the expression ∫ p dA for __________ processes.

A. Non-flow reversible

B. Adiabatic

C. Both (A) and (B)

D. Neither (A) nor (B)

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An ideal liquid refrigerant should

A. Not have a sub-atmospheric vapour pressure at the temperature in the refrigerator coils

B. Not have unduly high vapour pressure at the condenser temperature

C. Both (A) and (B)

D. Have low specific heat

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One ton of refrigeration capacity is equivalent to the heat removal rate of

A. 50 kcal/hr

B. 200 BTU/hr

C. 200 BTU/minute

D. 200 BTU/day

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Clapeyron Equation deals with the

A. Rate of change of vapour pressure with temperature

B. Effect of an inert gas on vapour pressure

C. Calculation of ΔF for spontaneous phase change

D. Temperature dependence of heat of phase transition

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Joule-Thomson co-efficient which is defined as, η = (∂T/∂P)H = 1/Cp (∂H/∂T)P, changes sign at a temperature known as inversion temperature. The value of Joule-Thomson co-efficient at inversion temperature is

A. 0

B.

C. +ve

D. -ve

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Lowering of condenser temperature (keeping the evaporator temperature constant) in case of vapour compression refrigeration system results in

A. Increased COP

B. Same COP

C. Decreased COP

D. Increased or decreased COP; depending upon the type of refrigerant

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Mollier chart is a __________ plot.

A. Pressure vs. enthalpy

B. Pressure vs. volume

C. Enthalpy vs. entropy

D. Temperature vs. entropy

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Pick out the wrong statement.

A. The values of (∂P/∂V)T and (∂2P/∂V2)T are zero for a real gas at its critical point

B. Heat transferred is equal to the change in the enthalpy of the system, for a constant pressure, non-flow, mechanically reversible process

C. Thermal efficiency of a Carnot engine depends upon the properties of the working fluid besides the source & sink temperatures

D. During a reversible adiabatic process, the entropy of a substance remains constant

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The unity of Planck's constant 'h' in the equation, E = hv is

A. J/s

B. J.S

C. J/kmol

D. kmol/J

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Claude's liquefaction process employs the cooling of gases by

A. Expansion in an engine

B. Following a constant pressure cycle

C. Throttling

D. None of these

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The point at which all the three (solid, liquid and gas) phases co-exist, is known as the __________ point.

A. Freezing

B. Triple

C. Boiling

D. Boyle

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The equation, (d loge PA/d loge xA) = (d loge PA/d loge xB) applicable to a binary solution of components. A and B in equilibrium with their vapors at constant temperature and pressure is called the __________ equation.

A. Van Laar

B. Margules

C. Gibbs-Duhem

D. Gibbs-Duhem-Margules

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Choose the condition that must be specified in order to liquify CO2 (triple point for CO2 is - 57°C and 5.2 atm).

A. Pressure must be kept below 5.2 atm

B. Temperature must be kept above - 57°C

C. Pressure must be kept below 5.2 atm. and temperature must be kept above 57°C

D. Pressure and temperature must be kept below 5.2 atm. and - 57°C respectively

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Maximum work that could be secured by expanding the gas over a given pressure range is the __________ work.

A. Isothermal

B. Adiabatic

C. Isentropic

D. None of these

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Change of heat content when one mole of compound is burnt in oxygen at constant pressure is called the

A. Calorific value

B. Heat of reaction

C. Heat of combustion

D. Heat of formation

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Thermal efficiency of a Carnot engine can approach 100%, only when the temperature of the

A. Cold reservoir approaches zero

B. Hot reservoir approaches infinity

C. Either (A) or (B)

D. Neither (A) nor (B)

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Gibbs-Duhem equation

A. States that n11 + n22 + ....njj = 0, for a system of definite composition at constant temperature and pressure

B. Applies only to binary systems

C. Finds no application in gas-liquid equilibria involved in distillation

D. None of these

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Work done is a

A. Property of the system

B. Path function

C. Point function

D. State description of a system

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The second law of thermodynamics states that

A. The energy change of a system undergoing any reversible process is zero

B. It is not possible to transfer heat from a lower temperature to a higher temperature

C. The total energy of system and surrounding remains the same

D. None of the above

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What is the ratio of adiabatic compressibility to isothermal compressibility?

A. 1

B. < 1

C. > 1

D. >> 1