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4

Which of the following is Clausius-Clapeyron Equation for vaporisation of an ideal gas under the condition that the molar volume of liquid is negligible compared to that of the vapor?

A. d ln p/dt = Hvap/RT2

B. d ln p/dt = RT2/Hvap

C. dp/dt = RT2/Hvap

D. dp/dt = Hvap/RT2

Correct Answer :

A. d ln p/dt = Hvap/RT2


Related Questions

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The equation relating E, P, V and T which is true for all substances under all conditions is given by (∂E/∂V)T = T(∂P/∂T)H - P. This equation is called the

A. Maxwell's equation

B. Thermodynamic equation of state

C. Equation of state

D. Redlich-Kwong equation of state

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4

The co-efficient of performance (COP) of a refrigerating system, which is its index of performance, is defined as the ratio of useful refrigeration to the net work. The units of __________ and COP are the same.

A. Kinematic viscosity

B. Work

C. Temperature

D. None of these

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4

Internal energy of an element at 1 atm and 25° C is __________ kcal/kg.mole.

A. 0

B. 273

C. 25

D. None of these

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Clapeyron Equation deals with the

A. Rate of change of vapour pressure with temperature

B. Effect of an inert gas on vapour pressure

C. Calculation of ΔF for spontaneous phase change

D. Temperature dependence of heat of phase transition

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4

Refrigeration capacity of a household refrigerator may be round about __________ tons.

A. 0.15

B. 1.5

C. 4.5

D. 6.5

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4

Entropy change of the reaction, H2O (liquid) → H2O (gas), is termed as the enthalpy of

A. Solution

B. Vaporisation

C. Formation

D. Sublimation

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4

The value of Joule-Thomson co-efficient, in case where cooling occurs after the throttling process is

A. 0

B.

C. +ve

D. -ve

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4

Out of the following refrigeration cycles, which one has maximum COP?

A. Air cycle

B. Carnot cycle

C. Ordinary vapor compression cycle

D. Vapor compression with a reversible expansion engine

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4

What happens in a reversible adiabatic expansion process?

A. Heating takes place

B. Cooling takes place

C. Pressure is constant

D. Temperature is constant

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4

Pick out the wrong statement.

A. Surface tension of a substance vanishes at critical point, as there is no distinction between liquid and vapour phases at its critical point

B. Entropy of a system decreases with the evolution of heat

C. Change of internal energy is negative for exothermic reactions

D. The eccentric factor for all materials is always more than one

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4

Work done in an adiabatic process between two states depends on the

A. Rate of heat transmission

B. Initial state only

C. End states only

D. None of these

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4

A system undergoes a change from a given initial state to a given final state either by an irreversible process or by a reversible process, then (where, Δ S1 and Δ SR are the entropy changes of the system for the irreversible and reversible processes respectively)

A. Δ S1 is always < Δ SR

B. Δ S1 is sometimes > Δ SR

C. Δ S1 is always > Δ SR

D. Δ S1 is always = Δ SR

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4

During a reversible isothermal expansion of an ideal gas, the entropy change is

A. +ve

B. 0

C. -ve

D.

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4

The work done in an adiabatic change in a particular gas depends upon changes in the __________ only.

A. Temperature

B. Specific heat

C. Volume

D. Pressure

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4

A/an __________ system is exemplified by a vessel containing a volatile liquid in contact with its vapor.

A. Isolated

B. Closed

C. Open

D. None of these

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4

Enthalpy of a gas depends upon its

A. Temperature

B. Mass

C. Volume

D. Pressure

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4

With increase in temperature, the atomic heat capacities of all solid elements

A. Increases

B. Decreases

C. Remains unchanged

D. Decreases linearly

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4

Molar heat capacity of water in equilibrium with ice at constant pressure is __________ Kcal/kg mole. °K

A. 0

B.

C. 50

D. 100

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4

Heat requirement for decomposition of a compound into its elements is __________ that is evolved during the formation of that compound from its elements.

A. The same

B. Less than

C. Greater than

D. Different than

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4

Pick out the wrong statement.

A. System (of partially miscible liquid pairs), in which the mutual solubility increases with rise in temperature, are said to possess an upper consolute temperature

B. Systems, in which the mutual solubility increases with decrease in temperature, are said to possess lower consolute temperature

C. Nicotine-water system shows both an upper as well as a lower consolute temperature, implying that they are partially miscible between these two limiting temperatures

D. None of these

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4

For an ideal gas, the internal energy depends upon its __________ only.

A. Molecular size

B. Temperature

C. Volume

D. Pressure

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4

Which of the following exemplifies an adiabatic process?

A. Melting of ice

B. Condensation of alcohol vapor

C. Sudden bursting of a cycle tube

D. Evaporation of water

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4

A gas performs the maximum work, when it expands

A. Non-uniformly

B. Adiabatically

C. Isobarically

D. Isothermally

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4

The fugacity of a gas in a mixture is equal to the product of its mole fraction and its fugacity in the pure state at the total pressure of the mixture. This is

A. The statement as per Gibbs-Helmholtz

B. Called Lewis-Randall rule

C. Henry's law

D. None of these

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4

Free energy changes for two reaction mechanism 'X' and 'Y are respectively - 15 and - 5 units. It implies that X is

A. Slower than Y

B. Faster than Y

C. Three times slower than Y

D. Three times faster than Y

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4

In a reversible process

A. Tds = dE + dW

B. dE - dW = Tds

C. dW - dE = Tds

D. Tds - dW + dE >0

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4

It is desired to bring about a certain change in the state of a system by performing work on the system under adiabatic conditions.

A. The amount of work needed is path dependent

B. Work alone cannot bring out such a change of state

C. The amount of work needed is independent of path

D. More information is needed to conclude anything about the path dependence or otherwise of the work needed

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4

The equation DU = Tds - PdV is applicable to infinitesimal changes occuring in

A. An open system of constant composition

B. A closed system of constant composition

C. An open system with changes in composition

D. A closed system with changes in composition

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4

Degree of freedom of a system consisting of a gaseous mixture of H2 and NH3 will be

A. 0

B. 1

C. 2

D. 3

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The work done in isothermal compression compared to that in adiabatic compression will be

A. Less

B. More

C. Same

D. More or less depending upon the extent of work done