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4

With increase in temperature, the internal energy of a substance

A. Increases

B. Decreases

C. Remains unchanged

D. May increase or decrease; depends on the substance

Correct Answer :

A. Increases


Related Questions

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4

For an ideal liquid solution, which of the following is unity?

A. Activity

B. Fugacity

C. Activity co-efficient

D. Fugacity co-efficient

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4

At the critical point of a substance

A. The surface tension vanishes

B. Liquid and vapour have the same density

C. There is no distinction between liquid and vapour phases

D. All (A), (B) and (C)

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4

One ton of refrigeration capacity is equivalent to the heat removal rate of

A. 50 kcal/hr

B. 200 BTU/hr

C. 200 BTU/minute

D. 200 BTU/day

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4

The intensive properties are

A. Molar volume, density, viscosity and boiling point

B. Refractive index and surface tension

C. Both (A) and (B)

D. None of these

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4

(∂H/∂T)P is the mathematical expression for

A. CV

B. Entropy change

C. Gibbs free energy

D. None of these

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4

Number of degrees of freedom for a three phase system in equilibrium comprising of three nonreacting chemical species is

A. 2

B. 0

C. 1

D. 3

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4

Consider the reaction, C + O2 CO2; ΔH = - 94 kcal. What will be the value of ΔH for the reaction CO2 → C + O2?

A. -94 kcal

B. +94 kcal

C. > 94 kcal

D. < -94 kcal

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4

The quantitative effect of temperature on chemical equilibrium is given by the

A. Vant-Hoff equation

B. Le-Chatelier's principle

C. Arrhenius equation

D. None of these

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4

Which law of the thermodynamics provides basis for measuring the thermodynamic property?

A. First law

B. Zeroth law

C. Third law

D. Second law

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4

Clausius-Clapeyron Equation gives accurate result, when the

A. Vapour pressure is relatively low and the temperature does not vary over wide limits

B. Vapour obeys the ideal gas law and the latent heat of vaporisation is constant

C. Volume in the liquid state is negligible compared with that in the vapour state

D. All (A), (B) and (C)

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4

As the time is passing, entropy of the universe

A. Is increasing

B. Is decreasing

C. Remain constant

D. Data insufficient, can't be predicted

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4

The ammonia synthesis reaction represented by N2 + 3H2 2NH3; ΔH = - 22.4 kcal, is

A. Endothermic

B. Exothermic

C. Isothermal

D. Adiabatic

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4

Internal energy change of a system over one complete cycle in a cyclic process is

A. Zero

B. +ve

C. -ve

D. Dependent on the path

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4

Activity co-efficient is a measure of the

A. Departure from ideal solution behaviour

B. Departure of gas phase from ideal gas law

C. Vapour pressure of liquid

D. None of these

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4

All gases during throttling process at atmospheric temperature and pressure show a cooling effect except

A. CO2

B. H2

C. O2

D. N2

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4

__________ law of thermodynamics ascertains the direction of a particular spontaneous process.

A. Zeroth

B. First

C. Second

D. Third

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4

Which of the following processes cannot be made reversible even under ideal condition of operation?

A. Free expansion of a gas

B. Compression of air in a compressor

C. Expansion of steam in a turbine

D. All (A), (B) & (C)

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4

The internal energy of a gas obeying P (V - b) RT (where, b is a positive constant and has a constant Cv), depends upon its

A. Pressure

B. Volume

C. Temperature

D. All (A), (B) & (C)

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4

Degree of freedom of the system ice-watervapour will be

A. 0

B. 1

C. 2

D. 3

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4

Change of state namely evaporation condensation, freezing and melting is an __________ process.

A. Isothermal

B. Adiabatic

C. Isobaric

D. Isochoric

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4

Cp - Cv = R is valid for __________ gases.

A. Ideal

B. Very high pressure

C. Very low temperature

D. All of the above

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4

__________ does not change during phase transformation processes like sublimation, melting & vaporisation.

A. Entropy

B. Gibbs free energy

C. Internal energy

D. All (A), (B) & (C)

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4

Pick out the extensive property out of the following.

A. Surface tension

B. Free energy

C. Specific heat

D. Refractive index

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4

In a P-V diagram (for an ideal gas), an isothermal curve will coincide within adiabatic curve (through a point), when

A. Cp < Cv

B. Cp = Cv

C. Cp > Cv

D. C ≥ Cv

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4

For spontaneous changes in an isolated system (S = entropy)

A. ds = 0

B. ds <0

C. ds > 0

D. ds = Constant

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4

For a given substance at a specified temperature, activity is __________ to fugacity.

A. Directly proportional

B. Inversely proportional

C. Equal

D. None of these

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4

Dryness fraction of wet steam is defined as the ratio of mass of vapour in the mixture to the mass of mixture __________ calorimeter is not used for measuring the dryness fraction of steam.

A. Bomb

B. Separating

C. Bucket

D. Throttling

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4

In which of the following reaction equilibrium, the value of equilibrium constant Kp will be more than is Kc?

A. 2HI H2 + I2

B. N2O4 2NO2

C. 2SO2 + O2 2SO3

D. None of these

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4

Forward reaction will be favoured for the exothermic reaction, represented by CO + H2O CO2 + H2, by

A. Low temperature and high pressure

B. Low temperature and low pressure

C. High temperature and high pressure

D. High temperature and low pressure

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4

A solid is transformed into vapour without going to the liquid phase at

A. Triple point

B. Boiling point

C. Below triple point

D. Always