Adiabatic
Isothermal
Isometric
None of these
B. Isothermal
Simultaneous pressure & temperature change
Heating
Cooling
Both (B) and (C)
Less
More
Same
More or less depending upon the extent of work done
System (of partially miscible liquid pairs), in which the mutual solubility increases with rise in temperature, are said to possess an upper consolute temperature
Systems, in which the mutual solubility increases with decrease in temperature, are said to possess lower consolute temperature
Nicotine-water system shows both an upper as well as a lower consolute temperature, implying that they are partially miscible between these two limiting temperatures
None of these
Below
At
Above
Either 'b' or 'c'
Virial co-efficients are universal constants
Virial co-efficients 'B' represents three body interactions
Virial co-efficients are function of temperature only
For some gases, Virial equations and ideal gas equations are the same
Extensive property
Intensive property
Force which drives the chemical system to equilibrium
Both (B) and (C)
Molecular size
Volume
Pressure
Temperature
At constant pressure
By throttling
By expansion in an engine
None of these
F = E - TS
F = H - TS
F = H + TS
F = E + TS
-94 kcal
> -94 kcal
< - 94 kcal
Zero
Is increasing
Is decreasing
Remain constant
Data insufficient, can't be predicted
Pressure to critical pressure
Critical pressure to pressure
Pressure to pseudocritical pressure
Pseudocritical pressure to pressure
dP/dT = ΔH/TΔV
ln P = - (ΔH/RT) + constant
ΔF = ΔH + T [∂(ΔF)/∂T]P
None of these
Disorder
Orderly behaviour
Temperature changes only
None of these
Adiabatic
Isometric
Isentropic
Isothermal
Zero
Unity
Infinity
None of these
(∂T/∂V)S = (∂p/∂S)V
(∂T/∂P)S = (∂V/∂S)P
(∂P/∂T)V = (∂S/∂V)T
(∂V/∂T)P = -(∂S/∂P)T
Isothermal compression
Isothermal expansion
Adiabatic expansion
Adiabatic compression
Le-Chatelier principle
Kopp's rule
Law of corresponding state
Arrhenius hypothesis
0
1
2
3
Two temperatures only
Pressure of working fluid
Mass of the working fluid
Mass and pressure both of the working fluid
Heating occurs
Cooling occurs
Pressure is constant
Temperature is constant
The concentration of each component should be same in the two phases
The temperature of each phase should be same
The pressure should be same in the two phases
The chemical potential of each component should be same in the two phases
Solubility increases as temperature increases
Solubility increases as temperature decreases
Solubility is independent of temperature
Solubility increases or decreases with temperature depending on the Gibbs free energy change of solution
1
2
3
0
Temperature
Mass
Volume
Pressure
Ethyl chloride or methyl chloride
Freon-12
Propane
NH3 or CO2
Tds = dE - dW = 0
dE - dW - Tds = 0
Tds - dE + dW < 0
Tds - dT + dW < 0
+ve
-ve
0
∞
Isothermal
Isentropic
Isobaric
Adiabatic