Stirling
Brayton
Rankine
None of these
A. Stirling
Volume
Pressure
Temperature
All a, b & c
Surface tension
Free energy
Specific heat
Refractive index
It is exothermic
It is isenthalpic
It takes place isothermally
It takes place at constant volume
Reversible and isothermal
Isothermal and irreversible
Reversible and adiabatic
Adiabatic and irreversible
Increase
Decrease
Remain unaltered
Increase or decrease; depends on the particular reaction
Volume of the liquid phase is negligible compared to that of vapour phase
Vapour phase behaves as an ideal gas
Heat of vaporisation is independent of temperature
All (A), (B) & (C)
100
50
205
200
0.5
3.5
4.5
8.5
Fugacity
Partial pressure
Activity co-efficient
All (A), (B), and (C)
0.15
1.5
4.5
6.5
RT d ln P
RT d ln f
R d ln f
None of these
Enhanced COP
Decreased COP
No change in the value of COP
Increased or decreased COP; depending upon the type of refrigerant
(∂E/∂T)V
(∂E/∂V)T
(∂E/∂P)V
(∂V/∂T)P
5 & 3
3.987 & 1.987
1.987 & 0.66
0.66 & 1.987
Vapour pressure is relatively low and the temperature does not vary over wide limits
Vapour obeys the ideal gas law and the latent heat of vaporisation is constant
Volume in the liquid state is negligible compared with that in the vapour state
All (A), (B) and (C)
Sub-cooled
Saturated
Non-solidifiable
None of these
Δ S1 is always < Δ SR
Δ S1 is sometimes > Δ SR
Δ S1 is always > Δ SR
Δ S1 is always = Δ SR
Minimum number of degree of freedom of a system is zero
Degree of freedom of a system containing a gaseous mixture of helium, carbon dioxide and hydrogen is 4
For a two phase system in equilibrium made up of four non-reacting chemical species, the number of degrees of freedom is 4
Enthalpy and internal energy change is zero during phase change processes like melting, vaporisation and sublimation
Equilibrium cannot be established
More ice will be formed
More water will be formed
Evaporation of water will take place
A real gas on expansion in vacuum gets heated up
An ideal gas on expansion in vacuum gets cooled
An ideal gas on expansion in vacuum gets heated up
A real gas on expansion in vacuum cools down whereas ideal gas remains unaffected
0°C and 750 mm Hg
15°C and 750 mm Hg
0°C and 1 kgf/cm2
15°C and 1 kgf/cm2
PV
2PV
PV/2
0
Entropy
Temperature
Enthalpy
Pressure
0
∞
+ve
-ve
Expansion valve
Condenser
Refrigerator
Compressor
Increase the partial pressure of H2
Increase the partial pressure of I2
Increase the total pressure and hence shift the equilibrium towards the right
Not affect the equilibrium conditions
A . x22
Ax1
Ax2
Ax12
Ethyl chloride or methyl chloride
Freon-12
Propane
NH3 or CO2
ΔF = ΔH + T [∂(ΔF)/∂T]P
ΔF = ΔH - TΔT
d(E - TS) T, V < 0
dP/dT = ΔHvap/T.ΔVvap
Moisture free ice
Solid helium
Solid carbon dioxide
None of these