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4

An ideal monatomic gas is taken round the cycle ABCDA as shown below in the P-V diagram. The work done during the cycle is

A. PV

B. 2PV

C. PV/2

D. 0

Correct Answer :

A. PV


Related Questions

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4

Fugacity is a measure of the

A. Escaping tendencies of the same substance in different phases of a system

B. Relative volatility of a mixture of two miscible liquids

C. Behaviour of ideal gases

D. None of these

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4

When pressure is applied on the system, ice ↔ water, then

A. Equilibrium cannot be established

B. More ice will be formed

C. More water will be formed

D. Evaporation of water will take place

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4

In Joule-Thomson porous plug experiment, the

A. Enthalpy does not remain constant

B. Entire apparatus is exposed to surroundings

C. Temperature remains constant

D. None of these

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4

Which of the following is an extensive property of a system?

A. Heat capacity

B. Molal heat capacity

C. Pressure

D. Concentration

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4

dW and dq are not the exact differential, because q and W are

A. State functions

B. Path functions

C. Intensive properties

D. Extensive properties

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4

Gibbs free energy at constant pressure and temperature under equilibrium conditions is

A.

B. 0

C. Maximum

D. Minimum

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4

Isentropic process means a constant __________ process.

A. Enthalpy

B. Pressure

C. Entropy

D. None of these

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4

For an ideal gas, the activity co-efficient is

A. Directly proportional to pressure

B. Inversely proportional to pressure

C. Unity at all pressures

D. None of these

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4

The rate at which a substance reacts is proportional to its active mass and the rate of a chemical reaction is proportional to the product of active masses of the reacting substances. This is the

A. Lewis-Randall rule

B. Statement of Van't Hoff Equation

C. Le-Chatelier's principle

D. None of these

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4

Measurement of thermodynamic property of temperature is facilitated by __________ law of thermodynamics.

A. 1st

B. Zeroth

C. 3rd

D. None of these

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4

Free energy changes for two reaction mechanism 'X' and 'Y are respectively - 15 and - 5 units. It implies that X is

A. Slower than Y

B. Faster than Y

C. Three times slower than Y

D. Three times faster than Y

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4

If two gases have same reduced temperature and reduced pressure, then they will have the same

A. Volume

B. Mass

C. Critical temperature

D. None of these

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4

Sublimation temperature of dry ice (solid CO2) is __________ °C.

A. -273

B. 0

C. -78

D. 5

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4

Chemical potential of ith component of a system is given by

A. μi = (∂F/∂ni)T, P, ni

B. μi = (∂A/∂ni)T, P, ni

C. μi = (∂F/∂ni)T, P

D. μi = (∂A/∂ni)T, P

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4

Pick out the Clausius-Clapeyron equation from the following:

A. dP/dT = ΔH/TΔV

B. ln P = - (ΔH/RT) + constant

C. ΔF = ΔH + T [∂(ΔF)/∂T]P

D. None of these

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4

Melting of ice is an example of an __________ process.

A. Adiabatic

B. Isothermal

C. Isometric

D. None of these

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4

The equation Tds = dE - PdV applies to

A. Single phase fluid of varying composition

B. Single phase fluid of constant composition

C. Open as well as closed systems

D. Both (B) and (C)

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4

For the gaseous phase chemical reaction, C2H4(g) + H2O(g) ↔ C2H5OH(g), the equilibrium conversion does not depend on the

A. Steam to ethylene ratio

B. Temperature

C. Pressure

D. None of these

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4

Van Laar equation deals with the activity coefficients in

A. Binary solutions

B. Ternary solutions

C. Azeotropic mixture only

D. None of these

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4

Which of the following is a widely used refrigerant in vapour compression refrigeration system (using large centrifugal compressor)?

A. Freon

B. Liquid sulphur dioxide

C. Methyl chloride

D. Ammonia

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4

The value of Cp & Cv respectively for monatomic gases in Kcal/kg Mole.°K are

A. 5 & 3

B. 3.987 & 1.987

C. 1.987 & 0.66

D. 0.66 & 1.987

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4

Which of the following is Clausius-Clapeyron Equation for vaporisation of an ideal gas under the condition that the molar volume of liquid is negligible compared to that of the vapor?

A. d ln p/dt = Hvap/RT2

B. d ln p/dt = RT2/Hvap

C. dp/dt = RT2/Hvap

D. dp/dt = Hvap/RT2

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4

Heat is added at constant pressure in an ideal __________ cycle.

A. Stirling

B. Brayton

C. Rankine

D. Both (B) and (C)

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4

Free energy change of mixing two liquid substances is a function of the

A. Concentration of the constituents only

B. Quantities of the constituents only

C. Temperature only

D. All (A), (B) and (C)

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4

Pick out the extensive property out of the following.

A. Surface tension

B. Free energy

C. Specific heat

D. Refractive index

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4

What is the ratio of adiabatic compressibility to isothermal compressibility?

A. 1

B. < 1

C. > 1

D. >> 1

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4

If we increase the pressure on a substance (which is at its triple point), then the triple point

A. Increases

B. Decreases

C. Remains unchanged

D. May increase or decrease; depends on the substance

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4

For an isothermal process, the internal energy of a gas

A. Increases

B. Decreases

C. Remains unchanged

D. Data insufficient, can't be predicted

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4

High __________ is an undesirable property for a good refrigerant.

A. Specific heat

B. Latent heat of vaporisation

C. Viscosity

D. Specific vapor volume

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4

With increase in reduced temperature, the fugacity co-efficient of a gas at constant reduced pressure

A. Increases

B. Decreases

C. Remain same

D. Decreases linearly