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4

In the reaction, represented by, 2SO2 + O2 2SO3; ΔH = - 42 kcal; the forward reaction will be favoured by

A. Low temperature

B. High pressure

C. Both (A) and (B)

D. Neither (A) nor (B)

Correct Answer :

C. Both (A) and (B)


Related Questions

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4

Clausius-Clapeyron Equation gives accurate result, when the

A. Vapour pressure is relatively low and the temperature does not vary over wide limits

B. Vapour obeys the ideal gas law and the latent heat of vaporisation is constant

C. Volume in the liquid state is negligible compared with that in the vapour state

D. All (A), (B) and (C)

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4

For an isothermal process, the internal energy of a gas

A. Increases

B. Decreases

C. Remains unchanged

D. Data insufficient, can't be predicted

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4

In reactions involving solids and liquids (where change in volume is negligible), the heat of reaction at constant pressure as compared to that at constant volume is

A. More

B. Less

C. Same

D. Unpredictable; depends on the particular reaction

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4

Pressure-enthalpy chart is useful in refrigeration. The change in internal energy of an ideal fluid used in ideal refrigeration cycle is

A. Positive

B. Negative

C. Zero

D. Infinity

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4

Trouton's ratio of __________ liquids is calculated using Kistyakowsky equation.

A. Polar

B. Non-polar

C. Both (A) & (B)

D. Neither (A) nor (B)

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4

When dilute aqueous solutions of two salts are mixed, the process is associated with

A. Decrease in temperature

B. Increase in temperature

C. No change in temperature

D. Change in temperature which is a function of composition

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4

The ammonia synthesis reaction represented by N2 + 3H2 2NH3; ΔH = - 22.4 kcal, is

A. Endothermic

B. Exothermic

C. Isothermal

D. Adiabatic

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4

The specific heat of saturated water vapour at 100°C is

A.

B. -ve

C. 0

D. +ve

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4

A gas shows deviation from ideal behaviour at

A. Low pressure and high temperature

B. Low pressure and low temperature

C. Low temperature and high pressure

D. High temperature and high pressure

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4

On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)s and the slope of the reversible isothermal line (∂P/ ∂V)T are related as (where, y = Cp/Cv)

A. (∂P/∂V)S = (∂P/∂V)T

B. (∂P/∂V)S = [(∂P/∂V)T]Y

C. (∂P/∂V)S = y(∂P/∂V)T

D. (∂P/∂V)S = 1/y(∂P/∂V)T

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4

Gibbs free energy (F) is defined as

A. F = E - TS

B. F = H - TS

C. F = H + TS

D. F = E + TS

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4

Which of the following is not an intensive property?

A. Volume

B. Density

C. Temperature

D. Pressure

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4

At normal boiling point, molar entropy of vaporisation is __________ Joule/K°.mole.

A. 72

B. 92

C. 142

D. 192

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Vapour which is at a pressure smaller than the saturation pressure for the temperature involved is called a __________ vapour.

A. Superheated

B. Desuperheated

C. Non-condensable

D. None of these

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4

Which of the following decreases with increase in pressure?

A. Melting point of ice

B. Melting point of wax

C. Boiling point of liquids

D. None of these

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4

Joule-Thomson Co-efficient at any point on the inversion curve is

A.

B. +ve

C. 0

D. -ve

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4

It is desired to bring about a certain change in the state of a system by performing work on the system under adiabatic conditions.

A. The amount of work needed is path dependent

B. Work alone cannot bring out such a change of state

C. The amount of work needed is independent of path

D. More information is needed to conclude anything about the path dependence or otherwise of the work needed

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4

Clapeyron Equation deals with the

A. Rate of change of vapour pressure with temperature

B. Effect of an inert gas on vapour pressure

C. Calculation of ΔF for spontaneous phase change

D. Temperature dependence of heat of phase transition

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4

The internal energy of an ideal gas is a function of its __________ only.

A. Molecular size

B. Volume

C. Pressure

D. Temperature

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4

Chemical potential of ith component of a system is given by

A. μi = (∂F/∂ni)T, P, ni

B. μi = (∂A/∂ni)T, P, ni

C. μi = (∂F/∂ni)T, P

D. μi = (∂A/∂ni)T, P

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4

In a homogeneous solution, the activity coefficient of a component depends upon the

A. Pressure

B. Composition

C. Temperature

D. All (A), (B) and (C)

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4

Heat requirement for decomposition of a compound into its elements is __________ that is evolved during the formation of that compound from its elements.

A. The same

B. Less than

C. Greater than

D. Different than

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4

Clausius-Clapeyron equation is applicable to __________ equilibrium processes.

A. Solid-vapor

B. Solid-liquid

C. Liquid-vapor

D. All (A), (B) and (C)

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4

Chemical potential (an intensive property) of a substance is a force that drives the chemical system to equilibrium and is equal to its partial molar properties. The ratio of chemical potential to free energy of a pure substance at constant temperature and pressure is

A. 0

B. 1

C.

D. None of these

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4

For an isothermal reversible compression of an ideal gas

A. Only ΔE = 0

B. Only ΔH =0

C. ΔE = ΔH = 0

D. dQ = dE

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4

Thermal efficiency of a Carnot engine can approach 100%, only when the temperature of the

A. Cold reservoir approaches zero

B. Hot reservoir approaches infinity

C. Either (A) or (B)

D. Neither (A) nor (B)

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4

Lowering of condenser temperature (keeping the evaporator temperature constant) in case of vapour compression refrigeration system results in

A. Increased COP

B. Same COP

C. Decreased COP

D. Increased or decreased COP; depending upon the type of refrigerant

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4

Which of the following diagrams does not represent an Otto cycle?

A.

B.

C.

D. None of these

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4

In a homogeneous solution, the fugacity of a component depends upon the

A. Pressure

B. Composition

C. Temperature

D. All (A), (B) and (C)

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4

The melting point of paraffin wax (which contracts on solidification) __________ with pressure rise.

A. Increases

B. Decreases

C. Remains unchanged

D. Decreases linearly