Related Questions
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4
The thermodynamic law, PVy = constant, is not applicable in case of
A. Ideal compression of air
B. Free expansion of an ideal gas
C. Adiabatic expansion of steam in a turbine
D. Adiabatic compression of a perfect gas
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4
When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change. This is called the
A. Le-Chatelier principle
C. Law of corresponding state
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4
At normal boiling point, molar entropy of vaporisation is __________ Joule/K°.mole.
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Measurement of thermodynamic property of temperature is facilitated by __________ law of thermodynamics.
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Variation of equilibrium pressure with temperature for any two phases of a given substances is given by the __________ equation.
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4
If the internal energy of an ideal gas decreases by the same amount as the work done by the system, then the
A. Process must be isobaric
B. Temperature must decrease
C. Process must be adiabatic
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For a cyclic process, a fixed ratio between heat and work
D. Is difficult to predict
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For a real gas, the chemical potential is given by
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For an ideal gas, the enthalpy
A. Increases with rise in pressure
B. Decreases with rise in pressure
C. Is independent of pressure
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The work done in isothermal compression compared to that in adiabatic compression will be
D. More or less depending upon the extent of work done
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Absolute zero temperature signifies the
A. Minimum temperature attainable
B. Temperature of the heat reservoir to which a Carnot engine rejects all the heat that is taken in
C. Temperature of the heat reservoir to which a Carnot engine rejects no heat
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4
Which of the following is not an equation of state?
B. Clausius-Clapeyron equation
C. Beattie-Bridgeman equation
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Cp of a gas at its critical temperature and pressure
D. Equals 0.24 kcal/kmol °K
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Gases are cooled in Joule-Thomson expansion, when it is __________ inversion temperature.
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4
Which of the following decreases with increase in pressure?
C. Boiling point of liquids
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4
Activity co-efficient is a measure of the
A. Departure from ideal solution behaviour
B. Departure of gas phase from ideal gas law
C. Vapour pressure of liquid
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A gas has a volume of 27.3 c.c. at 0°C. Its volume at 10°C (if pressure remains unchanged) will be __________ c.c.
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The work done in an adiabatic change in a particular gas depends upon changes in the __________ only.
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Critical compressibility factor for all substances
A. Are more or less constant (vary from 0.2 to 0.3)
B. Vary as square of the absolute temperature
C. Vary as square of the absolute pressure
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4
An ideal gas is taken around the cycle ABCA as shown in P-V diagram below: The work done by the gas during the cycle is equal to
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4
For an ideal gas, the activity co-efficient is
A. Directly proportional to pressure
B. Inversely proportional to pressure
C. Unity at all pressures
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4
__________ law of thermodynamics ascertains the direction of a particular spontaneous process.
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The rate at which a substance reacts is proportional to its active mass and the rate of a chemical reaction is proportional to the product of active masses of the reacting substances. This is the
B. Statement of Van't Hoff Equation
C. Le-Chatelier's principle
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__________ explains the equilibrium constant for any chemical reaction.
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Heat requirement for decomposition of a compound into its elements is __________ that is evolved during the formation of that compound from its elements.
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Heat of reaction at constant volume is identified with __________ change.
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In jet refrigerators, the refrigerating fluid is practically always
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Lowering of condenser temperature (keeping the evaporator temperature constant) in case of vapour compression refrigeration system results in
D. Increased or decreased COP; depending upon the type of refrigerant
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While dissolving a gas into a liquid at a constant temperature, the ratio of the concentration of the gas in the solution phase and in the gaseous phase is
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The partial pressure of each constituent present in an alloy is __________ the total vapor pressure exerted by the alloy.
D. Either (B) or (C); depends on the type of alloy