Related Questions
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The ratio of equilibrium constants (Kp2/Kp1) at two different temperatures is given by
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Which of the following is not a common refrigerant?
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When a gas is subjected to adiabatic expansion, it gets cooled due to
B. Decrease in temperature
C. Decrease in kinetic energy
D. Energy spent in doing work
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4
For a real gas, the chemical potential is given by
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A refrigerator works on the principle of __________ law of thermodynamics.
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For a thermodynamic system containing 'x' chemical species, the maximum number of phases that can co-exist at equilibrium is
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In case of steady flow compression polytropic process (PVn = constant), the work done on air is the lowest, when
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Number of phases in a colloidal system is:
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With increase in pressure (above atmospheric pressure), the Cp of a gas
D. First decreases and then increases
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The expression, ΔG = nRT. ln(P2/P1), gives the free energy change
A. With pressure changes at constant temperature
B. Under reversible isothermal volume change
C. During heating of an ideal gas
D. During cooling of an ideal gas
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Chemical potential is a/an
C. Force which drives the chemical system to equilibrium
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As the temperature is lowered towards the absolute zero, the value of the quantity (∂ΔF/∂T) approaches
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Isobaric process means a constant process.
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A system undergoes a change from a given initial state to a given final state either by an irreversible process or by a reversible process, then (where, Δ S1 and Δ SR are the entropy changes of the system for the irreversible and reversible processes respectively)
B. Δ S1 is sometimes > Δ SR
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Which of the following will increase the volume of a real gas by four times?
A. Doubling the absolute temperature as well as pressure of the gas
B. Reducing pressure to one fourth at constant temperature
C. Reducing temperature to one fourth at constant pressure
D. Reducing the temperature to half and doubling the pressure
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Entropy, which is a measure of the disorder of a system, is:
A. Independent of pressure
B. Independent of temperature
C. Zero at absolute zero temperature for a perfect crystalline substance
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When a system is in equilibrium for all possible processes, the differential or finite change of entropy is
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For spontaneous changes in an isolated system (S = entropy)
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Melting of ice exemplifies a/an
D. Process involving a chemical reaction
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At constant temperature and pressure, for one mole of a pure substance, the ratio of the free energy to the chemical potential is
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For a constant volume process __________ by the system is used only to increase the internal energy.
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In the decomposition of PCl5 represented by, PCl5 PCl3 + Cl2, decrease in the pressure of the system will __________ the degree of dissociation of PCl5.
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Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature.
D. Decreases logarithmically
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Pick out the Clausius-Clapeyron equation from the following:
B. ln P = - (ΔH/RT) + constant
C. ΔF = ΔH + T [∂(ΔF)/∂T]P
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For an incompressible fluid, the __________ is a function of both pressure as well as temperature.
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Heat of formation of an element in its standard state is
D. A function of pressure
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For an irreversible process involving only pressure-volume work
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An ideal gas is taken around the cycle ABCA as shown in P-V diagram below: The work done by the gas during the cycle is equal to
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A liquid under pressure greater than its vapour pressure for the temperature involved is called a __________ liquid.
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With increase in compression ratio, the efficiency of the otto engine