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4

Henry's law is closely obeyed by a gas, when its __________ is extremely high.

A. Pressure

B. Solubility

C. Temperature

D. None of these

Correct Answer :

D. None of these


Related Questions

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In a working refrigerator, the value of COP is always

A. 0

B. < 0

C. < 1

D. > 1

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4

When a system is in equilibrium for all possible processes, the differential or finite change of entropy is

A. < 0

B. > 0

C. = 0

D. None of these

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4

During adiabatic expansion of gas

A. Pressure remains constant

B. Pressure is increased

C. Temperature remains constant

D. None of these

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4

In the reaction, C + O2 → CO2; ΔH = - 94 kcal. What is the heat content (enthalpy) of O2?

A. -94 kcal

B. > -94 kcal

C. < - 94 kcal

D. Zero

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4

Pick out the extensive property out of the following.

A. Surface tension

B. Free energy

C. Specific heat

D. Refractive index

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For a constant volume process

A. dE = CpdT

B. dE = CvdT

C. dQ = dE + pdV

D. dW = pdV

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4

A/an __________ system is exemplified by a vessel containing a volatile liquid in contact with its vapor.

A. Isolated

B. Closed

C. Open

D. None of these

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Work done may be calculated by the expression ∫ p dA for __________ processes.

A. Non-flow reversible

B. Adiabatic

C. Both (A) and (B)

D. Neither (A) nor (B)

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4

Which of the following is Clausius-Clapeyron Equation for vaporisation of an ideal gas under the condition that the molar volume of liquid is negligible compared to that of the vapor?

A. d ln p/dt = Hvap/RT2

B. d ln p/dt = RT2/Hvap

C. dp/dt = RT2/Hvap

D. dp/dt = Hvap/RT2

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Domestic refrigerator usually works on the __________ refrigeration cycle.

A. Carnot

B. Air

C. Absorption

D. vapour-ejection

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4

Which is an example of closed system?

A. Air compressor

B. Liquid cooling system of an automobile

C. Boiler

D. None of these

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4

Gases are cooled in Joule-Thomson expansion, when it is __________ inversion temperature.

A. Below

B. At

C. Above

D. Either 'b' or 'c'

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For a spontaneous process, free energy

A. Is zero

B. Increases

C. Decreases whereas the entropy increases

D. And entropy both decrease

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4

Pick out the Clausius-Clapeyron equation from the following:

A. dP/dT = ΔH/TΔV

B. ln P = - (ΔH/RT) + constant

C. ΔF = ΔH + T [∂(ΔF)/∂T]P

D. None of these

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4

Third law of thermodynamics is helpful in

A. Prediction of the extent of a chemical reaction

B. Calculating absolute entropies of substances at different temperature

C. Evaluating entropy changes of chemical reaction

D. Both (B) and (C)

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4

The relation connecting the fugacities of various components in a solution with one another and to composition at constant temperature and pressure is called the __________ equation.

A. Gibbs-Duhem

B. Van Laar

C. Gibbs-Helmholtz

D. Margules

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4

Equation which relates pressure, volume and temperature of a gas is called the

A. Equation of state

B. Gibbs Duhem equation

C. Ideal gas equation

D. None of these

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4

Pick out the wrong statement.

A. Surface tension of a substance vanishes at critical point, as there is no distinction between liquid and vapour phases at its critical point

B. Entropy of a system decreases with the evolution of heat

C. Change of internal energy is negative for exothermic reactions

D. The eccentric factor for all materials is always more than one

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4

Which of the following is not an equation of state?

A. Bertholet equation

B. Clausius-Clapeyron equation

C. Beattie-Bridgeman equation

D. None of these

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4

Pick out the undesirable property for a good refrigerant.

A. High thermal conductivity

B. Low freezing point

C. Large latent heat of vaporisation

D. High viscosity

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4

The acentric factor of a materical, 'ω', is defined as ω = -log10(Prsat)Tr-1 = 0.7, where, Prsat = reduced vapor pressure, Tr = reduced temperature. The value of acentric factor is always

A. > 2

B. < 1

C. > 1

D. < 3

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4

The kinetic energy of gas molecule is zero at

A. 0°C

B. 273°C

C. 100°C

D. -273°C

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4

The chemical potential of any constituent of an ideal solution depends on the __________ of the solution.

A. Temperature

B. Pressure

C. Composition

D. All (A), (B) and (C)

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4

Isobaric process means a constant process.

A. Temperature

B. Pressure

C. Volume

D. Entropy

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Fundamental principle of refrigeration is based on the __________ law of thermodynamics.

A. Zeroth

B. First

C. Second

D. Third

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The unity of Planck's constant 'h' in the equation, E = hv is

A. J/s

B. J.S

C. J/kmol

D. kmol/J

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4

When pressure is applied on the system, ice ↔ water, then

A. Equilibrium cannot be established

B. More ice will be formed

C. More water will be formed

D. Evaporation of water will take place

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What happens in a reversible adiabatic compression?

A. Heating occurs

B. Cooling occurs

C. Pressure is constant

D. Temperature is constant

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During a reversible isothermal expansion of an ideal gas, the entropy change is

A. +ve

B. 0

C. -ve

D.

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Dry ice is

A. Moisture free ice

B. Solid helium

C. Solid carbon dioxide

D. None of these